… Asymmetric hydrosilylation of ketoximes is another reliable approach for this
transformation. Brunner and co-workers developed the rhodium-catalyzed asymmetric …

… vinyl acetates.[16] [17] The reaction of 1 with ethyl acrylate in MeCN resulted in Michael addition
of the hydroxy group of the oxime to … that the rhodium-catalyzed reactions of oximes with …

… Rhodium-catalyzed asymmetric hydrogenation of β-dehydroamino acid derivatives is a …
For example, the hydrogenation of N-protected imines or oxime acetates with the Rh complexes …

… (44−48) Here, we report Ir/Zhaophos-catalyzed asymmetric hydrogenation of oximes for the
… Initially, we examined the hydrogenation of oxime using (E)-1-phenylethan-1-one oxime (1a) …

… for rhodium-catalyzed reaction of α,β-unsaturated oximes … of the mechanisms of
rhodium-catalyzed C–H activation and … the oxime α-hydrogen atom occurs in the presence of …

… , methanol, ethyl acetate or even chloroform are used, no enantioselectivity was observed. …
be prepared from ubiquitous ketones via the oxime.Alternatively they can be prepared from …

… Previously, L8 had also been successfully applied to the rhodium-catalyzed AH of α,β-… for
the straightforward synthesis of chiral acetamides from oxime derivatives. After an exhaustive …

… center on the catalytic asymmetric hydrogenation of oximes,[4… Aprotic solvents such as THF,
DCM and ethyl acetate could … reaction conditions for the asymmetric hydrogenation of (E)-…

… In summary, a long-standing problem concerning the asymmetric hydrogenation of oximes
to chiral hydroxylamines has been resolved via a Ni-catalysed asymmetric hydrogenation in …

… The rhodium-catalyzed asymmetric hydrogenation of … the ketone to the corresponding oxime
and subsequent reductive … layer was extracted three times with ethyl acetate (50 mL). The …