Room-temperature methane activation by a bimetallic oxide cluster AlVO4+
Gas-phase room-temperature methane activation by various clusters draws increasing
attention. In this Letter, we produce a series of bimetallic oxide clusters which contain both
main-group metal aluminum atoms and transition-metal vanadium atoms. We provide solid
experimental and theoretical evidence that bimetallic AlVO4+ cluster can draw a hydrogen
atom from methane to produce CH3 at room temperature. The Al3VO7+ cluster which can be
considered as a system formed from Al2O3+ AlVO4+ does not break C–H bonds of …
attention. In this Letter, we produce a series of bimetallic oxide clusters which contain both
main-group metal aluminum atoms and transition-metal vanadium atoms. We provide solid
experimental and theoretical evidence that bimetallic AlVO4+ cluster can draw a hydrogen
atom from methane to produce CH3 at room temperature. The Al3VO7+ cluster which can be
considered as a system formed from Al2O3+ AlVO4+ does not break C–H bonds of …
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