Rotational effects in low energy dissociative recombination of diatomic ions
B Vâlcu, IF Schneider, M Raoult, C Strömholm… - The European Physical …, 1998 - Springer
B Vâlcu, IF Schneider, M Raoult, C Strömholm, M Larsson, A Suzor-Weiner
The European Physical Journal D-Atomic, Molecular, Optical and Plasma Physics, 1998•SpringerThe effect of rotational interaction in the low energy dissociative recombination process of
diatomic molecules has been explored for typical molecular ions () which sample a large
range of molecular masses. We show that rotation plays a role mainly for the indirect
recombination process through bound Rydberg states, and for light molecules. When the
direct process based on a strong electronic interaction is fast and dominating, rotational
couplings can be safely neglected especially for heavier molecules like NO.
diatomic molecules has been explored for typical molecular ions () which sample a large
range of molecular masses. We show that rotation plays a role mainly for the indirect
recombination process through bound Rydberg states, and for light molecules. When the
direct process based on a strong electronic interaction is fast and dominating, rotational
couplings can be safely neglected especially for heavier molecules like NO.
Abstract
The effect of rotational interaction in the low energy dissociative recombination process of diatomic molecules has been explored for typical molecular ions (\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}\end{document}) which sample a large range of molecular masses. We show that rotation plays a role mainly for the indirect recombination process through bound Rydberg states, and for light molecules. When the direct process based on a strong electronic interaction is fast and dominating, rotational couplings can be safely neglected especially for heavier molecules like NO.
Springer
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