Single-ion magnet behaviour in [U (Tp Me2) 2 I]
JT Coutinho, MA Antunes, LCJ Pereira, H Bolvin… - Dalton …, 2012 - pubs.rsc.org
Dalton Transactions, 2012•pubs.rsc.org
[U (TpMe2) 2I] exhibits at low temperatures single molecule magnet (SMM) behaviour
comparable to its bipyridine derivative and related single ion U (III) complexes recently
reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxation in
these compounds is well reproduced by quantum chemistry calculations.
comparable to its bipyridine derivative and related single ion U (III) complexes recently
reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxation in
these compounds is well reproduced by quantum chemistry calculations.
[U(TpMe2)2I] exhibits at low temperatures single molecule magnet (SMM) behaviour comparable to its bipyridine derivative and related single ion U(III) complexes recently reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxation in these compounds is well reproduced by quantum chemistry calculations.
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