Structural disorder, magnetism, and electrical and thermoelectric properties of pyrochlore Nd2Ru2O7
MW Gaultois, PT Barton, CS Birkel… - Journal of Physics …, 2013 - iopscience.iop.org
Journal of Physics: Condensed Matter, 2013•iopscience.iop.org
Abstract Polycrystalline Nd 2 Ru 2 O 7 samples have been prepared and examined using a
combination of structural, magnetic, and electrical and thermal transport studies. Analysis of
synchrotron x-ray and neutron diffraction patterns suggests some site disorder on the A-site
in the pyrochlore sublattice: Ru substitutes on the Nd-site up to 7.0 (3)%, regardless of the
different preparative conditions explored. Intrinsic magnetic and electrical transport
properties have been measured. Ru 4d spins order antiferromagnetically at 143 K, as seen …
combination of structural, magnetic, and electrical and thermal transport studies. Analysis of
synchrotron x-ray and neutron diffraction patterns suggests some site disorder on the A-site
in the pyrochlore sublattice: Ru substitutes on the Nd-site up to 7.0 (3)%, regardless of the
different preparative conditions explored. Intrinsic magnetic and electrical transport
properties have been measured. Ru 4d spins order antiferromagnetically at 143 K, as seen …
Abstract
Polycrystalline Nd 2 Ru 2 O 7 samples have been prepared and examined using a combination of structural, magnetic, and electrical and thermal transport studies. Analysis of synchrotron x-ray and neutron diffraction patterns suggests some site disorder on the A-site in the pyrochlore sublattice: Ru substitutes on the Nd-site up to 7.0 (3)%, regardless of the different preparative conditions explored. Intrinsic magnetic and electrical transport properties have been measured. Ru 4d spins order antiferromagnetically at 143 K, as seen both in the susceptibility and in the specific heat, and there is a corresponding change in the electrical resistivity. The onset of a second antiferromagnetic ordering transition seen below 5 K is attributed to ordering of Nd 4f spins. Nd 2 Ru 2 O 7 is an electrical insulator, and this behaviour is believed to be independent of the Ru-antisite disorder on the Nd-site. The electrical properties of Nd 2 Ru 2 O 7 are presented in the light of data published on all A 2 Ru 2 O 7 pyrochlores, and we emphasize the special structural role that Bi 3+ ions on the A-site play in driving metallic behaviour. High-temperature thermoelectric properties have also been measured. When considered in the context of known thermoelectric materials with useful figures-of-merit, it is clear that Nd 2 Ru 2 O 7 has excessively high electrical resistivity which prevents it from being an effective thermoelectric. A method for screening candidate thermoelectrics is suggested.
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