Structural evolution and skyrmionic phase diagram of the lacunar spinel

EC Schueller, DA Kitchaev, JL Zuo, JD Bocarsly… - Physical Review …, 2020 - APS
Physical Review Materials, 2020APS
In the AB 4 Q 8 lacunar spinels, the electronic structure is described on the basis of inter-and
intracluster interactions of tetrahedral B 4 clusters, and tuning these can lead to myriad
fascinating electronic and magnetic ground states. In this work, we employ magnetic
measurements, synchrotron x-ray and neutron scattering, and first-principles electronic
structure calculations to examine the coupling between structural and magnetic phase
evolution in GaMo 4 Se 8, including the emergence of a skyrmionic regime in the magnetic …
In the lacunar spinels, the electronic structure is described on the basis of inter- and intracluster interactions of tetrahedral clusters, and tuning these can lead to myriad fascinating electronic and magnetic ground states. In this work, we employ magnetic measurements, synchrotron x-ray and neutron scattering, and first-principles electronic structure calculations to examine the coupling between structural and magnetic phase evolution in , including the emergence of a skyrmionic regime in the magnetic phase diagram. We show that the competition between two distinct Jahn-Teller distortions of the room temperature cubic structure leads to the coexistence of the ground-state phase and a metastable phase. The magnetic properties of these two phases are computationally shown to be very different, with the phase exhibiting uniaxial ferromagnetism and the phase hosting a complex magnetic phase diagram including equilibrium Néel-type skyrmions stable from nearly  = 28 K down to  = 2 K, the lowest measured temperature. The large change in magnetic behavior induced by a small structural distortion reveals that is an exciting candidate material for tuning unconventional magnetic properties via mechanical means.
American Physical Society
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