Study of microscopic origin of segregation for FexCu1− x and CuxCo1− x liquid binary alloys

MM Faruk, GM Bhuiyan, A Biswas… - The Journal of Chemical …, 2014 - pubs.aip.org
The segregating properties for Fe x Cu 1− x and Cu x Co 1− x liquid-liquid binary alloys are
investigated theoretically. Here, the free energy of mixing is calculated by using the
electronic theory of metals within the framework of the perturbative approach. The calculated
results such as the critical temperature and the critical concentration agree well with the
available experimental data. Most importantly, the present work confirms our previous
finding [M. Mehedi Faruk and GM Bhuiyan, Physica B 422, 56 (2013)] that the volume …
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