Study of the reactivity of CpMCo (CO) 7 (M= Mo, W) complexes toward various alkynes

R Yanez, N Lugan, R Mathieu - Organometallics, 1990 - ACS Publications
R Yanez, N Lugan, R Mathieu
Organometallics, 1990ACS Publications
… vestigated the reactivity of these compounds toward various alkynes. We have observed
that these dinuclear complexes can … To conclude, the use of mixed CpMCo(CO)7 systems
has not put in evidence a new reactivity toward alkynes compared to that of the Co2(CO)8
and [CpM(CO)3]2 complexes. …
Summary
The CpMCo (CO) 7 complexes (M= Mo, W) react with alkynes in boiling hexane, leading to CpMCo-
ACS Publications
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