Substrate-induced covalent assembly of a chemzyme and crystallographic characterization of a chemzyme− substrate complex
G Hu, AK Gupta, RH Huang… - Journal of the …, 2010 - ACS Publications
G Hu, AK Gupta, RH Huang, M Mukherjee, WD Wulff
Journal of the American Chemical Society, 2010•ACS PublicationsA substrate induced covalent assembly of a highly organized chemzyme known to be
effective in both catalytic asymmetric aziridination and aza Diels− Alder reactions is
described and the information gained from which led to an efficient one-pot aziridination
protocol. The crystal structures of two chemzyme− iminium complexes were elucidated by X-
ray diffraction analysis that provides critical insights into the binding of the substrates with
the chemzyme.
effective in both catalytic asymmetric aziridination and aza Diels− Alder reactions is
described and the information gained from which led to an efficient one-pot aziridination
protocol. The crystal structures of two chemzyme− iminium complexes were elucidated by X-
ray diffraction analysis that provides critical insights into the binding of the substrates with
the chemzyme.
A substrate induced covalent assembly of a highly organized chemzyme known to be effective in both catalytic asymmetric aziridination and aza Diels−Alder reactions is described and the information gained from which led to an efficient one-pot aziridination protocol. The crystal structures of two chemzyme−iminium complexes were elucidated by X-ray diffraction analysis that provides critical insights into the binding of the substrates with the chemzyme.
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