Synthesis, characterization and weak ferromagnetic coupling in [Cu2 (μ3-CO3)(SCN) 2 (py) 4] n

A Vakulka, E Goreshnik, Z Jaglicic, Z Trontelj - Inorganic Chemistry …, 2013 - Elsevier
The crystal structure of a novel [Cu 2 (μ 3-CO 3)(SCN) 2 (py) 4] n complex has been
determined. It comprises of [Cusingle bondCO 3 single bondCu] n infinite chains, running
along the a-axis, and is in this aspect similar to the previously described [Cu (CO 3)(4-
aminopyridine) 2]· H 2 O complex. The FTIR spectrum of [Cu 2 (μ 3-CO 3)(SCN) 2 (py) 4] n
has been recorded and analyzed. A Cusingle bondCO 3 single bondCu intrachain coupling
between Cu (II) atoms has been found to be responsible for the weak ferromagnetic …
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