Synthesis of a green fuel additive over cation resins
The synthesis of polyoxymethylene dimethyl ethers (PODEn), being green diesel fuel
additives, from dimethoxymethane (DMM) and paraformaldehyde over three different cation
resins, namely NKC‐9, D001‐CC, and D72, in a stirred‐autoclave reactor was investigated.
The pore size distribution and surface area were measured with nitrogen adsorption‐
desorption. NKC‐9 had a larger exchange capacity, better developed porosity structure, and
higher reaction activity than D001‐CC and D72. The effects of reaction temperature …
additives, from dimethoxymethane (DMM) and paraformaldehyde over three different cation
resins, namely NKC‐9, D001‐CC, and D72, in a stirred‐autoclave reactor was investigated.
The pore size distribution and surface area were measured with nitrogen adsorption‐
desorption. NKC‐9 had a larger exchange capacity, better developed porosity structure, and
higher reaction activity than D001‐CC and D72. The effects of reaction temperature …
Abstract
The synthesis of polyoxymethylene dimethyl ethers (PODEn), being green diesel fuel additives, from dimethoxymethane (DMM) and paraformaldehyde over three different cation resins, namely NKC‐9, D001‐CC, and D72, in a stirred‐autoclave reactor was investigated. The pore size distribution and surface area were measured with nitrogen adsorption‐desorption. NKC‐9 had a larger exchange capacity, better developed porosity structure, and higher reaction activity than D001‐CC and D72. The effects of reaction temperature, DMM/CH2O molar ratio, reaction time, and catalyst loading were studied with NKC‐9. A possible mechanism was explored to describe the bond reorganizations during the reactions.
Wiley Online Library以上显示的是最相近的搜索结果。 查看全部搜索结果