Synthesis of polyaniline nanofibers by “nanofiber seeding”

X Zhang, WJ Goux, SK Manohar - Journal of the American …, 2004 - ACS Publications
Journal of the American Chemical Society, 2004ACS Publications
Seeding a conventional chemical oxidative polymerization of aniline with even very small
amounts of biological, inorganic, or organic nanofibers (usually< 1%) dramatically changes
the morphology of the resulting doped electronic polymer polyaniline from nonfibrillar
(particulate) to almost exclusively nanofibers. The nanoscale morphology of the original
seed template is transcribed almost quantitatively to the bulk precipitate. These findings
could have immediate impact in the design and development of high-surface area electronic …
Seeding a conventional chemical oxidative polymerization of aniline with even very small amounts of biological, inorganic, or organic nanofibers (usually <1%) dramatically changes the morphology of the resulting doped electronic polymer polyaniline from nonfibrillar (particulate) to almost exclusively nanofibers. The nanoscale morphology of the original seed template is transcribed almost quantitatively to the bulk precipitate. These findings could have immediate impact in the design and development of high-surface area electronic materials.
ACS Publications
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