In this paper we propose a new class of ternary Zero Correlation Zone (ZCZ) sequence sets based on binary ZCZ sequence sets construction. It is shown that the proposed ternary ZCZ sequence sets can reach the upper bound on the ZCZ sequences. The performance of the proposed sequences set in asynchronous Direct Sequence-Code Division Multiple Access (DS-CDMA) system is evaluated. In the simulation we used two types of channels: Additive White Gaussian Noise (AWGN) and frequency non-selective fading with AWGN noise. The proposed ternary ZCZ sequence sets show better results, in term of Bit Error Rate (BER), than Hayashi’s ternary ZCZ sequence sets.