Insights into the structure and transport of the lithium, sodium, magnesium, and zinc bis (trifluoromethansulfonyl) imide salts in ionic liquids

O Borodin, GA Giffin, A Moretti, JB Haskins… - The Journal of …, 2018 - ACS Publications
… lithium (Li + ), sodium (Na + ), magnesium (Mg 2+ ), and zinc (Zn 2+ ) cation coordination by
the TFSI – anions and ion transport properties in ionic liquid (IL)-based electrolytes. ILs have …

Mechanisms of magnesium ion transport in pyrrolidinium bis (trifluoromethanesulfonyl) imide-based ionic liquid electrolytes

S Jeremias, GA Giffin, A Moretti, S Jeong… - The Journal of …, 2014 - ACS Publications
… This manuscript describes the material and transport properties of these Mg 2+ –IL
electrolytes and ties these properties to the molecular organization of the mixtures. Using these …

Complex Nature of Ionic Coordination in Magnesium Ionic Liquid-Based Electrolytes: Solvates with Mobile Mg2+ Cations

GA Giffin, A Moretti, S Jeong… - The Journal of Physical …, 2014 - ACS Publications
… In this work, the ionic coordination of Mg 2+ with TFSI – in IL-based electrolytes is …
Studies on the physical and transport properties of Mg 2+ -IL electrolytes will be reported in …

Ionic liquid crystals

K Binnemans - Chemical Reviews, 2005 - ACS Publications
… the properties of liquid crystals and ionic liquids. Worldwide intense research activity in the
field of ionic liquids is … An overview of the most important mesophases is given in this section. …

A materials perspective on magnesium-ion-based solid-state electrolytes

PW Jaschin, Y Gao, Y Li, SH Bo - Journal of Materials Chemistry A, 2020 - pubs.rsc.org
… Consequently, the size of the anion plays an important role … -based magnesium salt or ionic
liquids. This possibility of … compared the ion transport properties of several classes of Mg and …

Designer ionic liquids for reversible electrochemical deposition/dissolution of magnesium

T Watkins, A Kumar, DA Buttry - Journal of the American Chemical …, 2016 - ACS Publications
… solvents, Mg 2+ is typically found as Mg(TFSI) 3 – . If polyether solvents or ionic liquid cations
Mg 2+ is large (eg, >5 or 6), the ether oxygens displace TFSI – , producing free TFSI – and …

[HTML][HTML] Ionic liquid-based electrolytes for aluminum/magnesium/sodium-ion batteries

N Zhu, K Zhang, F Wu, Y Bai, C Wu - Energy Material Advances, 2021 - spj.science.org
… of aluminum ion resulting in superior transport properties. … theory to explain the important
role of oxide film at the anode/… reversibly transport Mg 2+ ions, in which various Mg salts are …

Electrochemical and structural characterization of Mg ion intercalation into RuO2 using an ionic liquid electrolyte

TE Sutto, TT Duncan - Electrochimica acta, 2012 - Elsevier
important result is that the ionic liquid functioned well as an Mg 2+ transport medium, and
that the polished Mg ribbon was not tarnished or discolored after cycling in the ionic liquid. As …

A review of ionic liquid surface film formation on Mg and its alloys for improved corrosion performance

P Huang, JA Latham, DR MacFarlane, PC Howlett… - Electrochimica …, 2013 - Elsevier
… This finding plays an important role in future design of ILs for corrosion protection. … SHE),
and are then able to further react with Mg 2+ , forming insoluble deposits on the surface (eg, …

Challenges and Progress in Rechargeable MagnesiumIon Batteries: Materials, Interfaces, and Devices

D Wang, Z Zhang, Y Hao, H Jia, X Shen… - Advanced Functional …, 2024 - Wiley Online Library
… a crucial role in identifying the electroactive species, [Mg2(μ-… , ionic liquid was reported as
an efficient additive for Mg(OTf)… benefits of introducing an ionic liquid into the electrolyte to …