… The first examples of transition‐metal‐catalyzed phosphinoborations of C‐C multiple bonds
in which PC and BC bonds are formed in a single step are also disclosed; allenes react …

… a more comprehensive investigation into the phosphinoboration reaction and, to this end, …
1,2- and 1,4-phosphinoboration and future computational investigations will focus on exploring …

… Such phosphinoborations could be extended to reactions of Ph 2 PBcat and Ph 2 PBpin with
… In conclusion, the above reactions of phosphinoboranes with diazomethanes demonstrate …

… General procedure: Phosphinoboration reactions were carried out as described above.
Following the prescribed time, methanol (5 drops) was added and the solution was stirred for an …

… phosphinoboration of ketones, imines, aldehydes,22 N-heterocycles,23 and a series of
heteroallenes.24 In the present study, we describe the reactions … phosphinoboration reactions.27 …

… to develop a phosphinoboration reaction of internal alkynes. … an unprecedented trans
phosphinoboration reaction that adds … afforded the desired trans phosphinoboration product 2 a, …

… In the present manuscript, we document the utility of phosphinoboranes in reactions with
acyl-chlorides as a route to acyl phosphines. Further reactions with phosphinoboranes to give …

… The phenyl and methylene resonances of the phosphinoborate anion are readily … This
contention is supported by the reaction chemistry of 2 with TlPF6. Reaction of 2 with one …

… We are continuing to examine the range of new FLPs and FLP chemistry that can be derived
from the general utility of phosphinoboration reactions. The results of these studies will be …

… Reactions employing these metal complexes also generated unusual endo-dig cyclic
lactones not traditionally observed in these cyclisation reactions. For instance, reactions of 4-…