The ternary Al–Ce–Cu phase diagram in the aluminum-rich corner
NA Belov, AV Khvan - Acta Materialia, 2007 - Elsevier
NA Belov, AV Khvan
Acta Materialia, 2007•ElsevierThe phase diagram of the Al–Ce–Cu system in the aluminum-rich corner (concentrations up
to 35wt.% Cu and up to 16wt.% Ce) was studied. Phases and invariant reactions were
identified. Liquidus and solidus surfaces, three isothermal cross-sections (540, 590 and
200° C) and five vertical cross-sections were constructed. It was shown that Al4Ce
(Al11Ce3), Al8CeCu4 and Al2Cu were in equilibrium with the aluminum solid solution (Al). It
was determined that about 17wt.% Cu dissolves in Al4Ce; the existence of the Al4CeCu …
to 35wt.% Cu and up to 16wt.% Ce) was studied. Phases and invariant reactions were
identified. Liquidus and solidus surfaces, three isothermal cross-sections (540, 590 and
200° C) and five vertical cross-sections were constructed. It was shown that Al4Ce
(Al11Ce3), Al8CeCu4 and Al2Cu were in equilibrium with the aluminum solid solution (Al). It
was determined that about 17wt.% Cu dissolves in Al4Ce; the existence of the Al4CeCu …
The phase diagram of the Al–Ce–Cu system in the aluminum-rich corner (concentrations up to 35wt.% Cu and up to 16wt.% Ce) was studied. Phases and invariant reactions were identified. Liquidus and solidus surfaces, three isothermal cross-sections (540, 590 and 200°C) and five vertical cross-sections were constructed. It was shown that Al4Ce (Al11Ce3), Al8CeCu4 and Al2Cu were in equilibrium with the aluminum solid solution (Al). It was determined that about 17wt.% Cu dissolves in Al4Ce; the existence of the Al4CeCu phase was not confirmed. Experimentally determined parameters of the invariant quasi-binary eutectic reaction L→(Al)+Al8CeCu4 (610°C, 14wt.% Cu and 7wt.% Ce) were essentially different from those published earlier. This eutectic had a fine microstructure and was stable to coarsening (after fragmentation and spheroidizing) during the heating process even though the average particle size did not grow larger than 2μm after annealing at 590°C.
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