Thermal degradation study of poly (vinyl chloride): kinetic analysis of thermogravimetric data

A Jimenez, V Berenguer, J Lopez… - Journal of Applied …, 1993 - Wiley Online Library
A Jimenez, V Berenguer, J Lopez, A Sanchez
Journal of Applied Polymer Science, 1993Wiley Online Library
The thermal degradation of a poly (vinyl chloride)(PVC) resin was studied using a non‐
isothermal thermogravimetric technique. Kinetic parameters such as activation energies,
reaction orders, and preexponential factors are calculated using integral and differential
methods reported in the literature. Advantages and disadvantages of these methods are
discussed in order to characterize PVC.© 1993 John Wiley & Sons, Inc.
Abstract
The thermal degradation of a poly(vinyl chloride) (PVC) resin was studied using a non‐isothermal thermogravimetric technique. Kinetic parameters such as activation energies, reaction orders, and preexponential factors are calculated using integral and differential methods reported in the literature. Advantages and disadvantages of these methods are discussed in order to characterize PVC. © 1993 John Wiley & Sons, Inc.
Wiley Online Library
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