Stereodynamics of acyclic alcohols, ethers, and N, N-dimethylurethanes. Potential barriers to rotation about carbon-carbon and carbon-nitrogen bonds

S Hoogasian, CH Bushweller… - The Journal of …, 1976 - ACS Publications
… the DNMR measurement of the rate of tert-butyl rotation in a series of selectively deuterated
acyclic alcohols, methyl ethers, and urethanes. The tert-butyl rotor was selected in order to …

Stereocontrolled formation of several carboncarbon bonds in acyclic systems

G Eppe, D Didier, I Marek - Chemical Reviews, 2015 - ACS Publications
… heteroelements such as oxygen, sulfur, and nitrogen in ortho position could lead to yields up
to … carbon center to give 90 that could be oxidized with retention of configuration into alcohol

Asymmetric reductions of carbon-nitrogen double bonds. A review

QC Zhu, RO Hutchins, MK Hutchins - Organic preparations and …, 1994 - Taylor & Francis
… 2, Reductions of Acyclic [mines A fruitful approach to the synthesis of acyclic 2-amin0
alcohol diastereomers involves reaction of silylether protected cyanohydrins (23) with Grignard …

Carbon dioxide and molecular nitrogen as switches between ionic and uncharged room-temperature liquids comprised of amidines and chiral amino alcohols

T Yu, T Yamada, GC Gaviola, RG Weiss - Chemistry of Materials, 2008 - ACS Publications
… Neat 1.0 mm path length samples of both with A molecules containing acyclic, saturated
side groups are almost completely transparent above 300 nm (Supporting Information Figure …

Asymmetric Ring‐Opening of Cyclopropyl Ketones with Thiol, Alcohol, and Carboxylic Acid Nucleophiles Catalyzed by a Chiral N,N′‐Dioxide–Scandium(III) …

Y Xia, L Lin, F Chang, X Fu, X Liu… - Angewandte Chemie, 2015 - Wiley Online Library
carbon chains of alcohols had no obvious influence on the enantioselectivities (entries 1–4).
Besides the acyclic substituted alcohols, cyclic substituted alcohols … for 0.5 h under nitrogen

… synthesis at nitrogen by oxidation of imines with m-chloroperbenioic acid in the presence of optically active carbinols. Absolute stereochemistry of chiral alcohol-imine …

M Bucciarelli, A Forni, I Moretti, G Torre - Journal of the Chemical …, 1980 - pubs.rsc.org
alcohols are used as the chiral media; for instance, oxidation of sulphides in the presence of
chiral alcohols … out in the presence of acyclic or cyclic aliphatic alcohols ; the optical purity of …

Chromatographic determination of the absolute configuration of an acyclic secondary alcohol using difluorodinitrobenzene

K Harada, Y Shimizu, A Kawakami… - Analytical …, 2000 - ACS Publications
… substituents of the alcohol and leucinamide moieties, the … applied to various chiral acyclic
secondary alcohols including … the auxiliary and sheath gas nitrogen pressure set at 5 units …

1, 2-Amino alcohols and their heterocyclic derivatives as chiral auxiliaries in asymmetric synthesis

DJ Ager, I Prakash, DR Schaad - Chemical Reviews, 1996 - ACS Publications
alcohols provide for nucleophilic substitution under Mitsunobu conditions with the stereochemistry
controlled by the nitrogen … Although not derived from an acyclic amino alcohol, the …

Addition of water and ammonia to the carboncarbon double bond of acyclic alkenes and strained bicyclic dienes; a computational study

HF Koch, LA Girard, DM Roundhill - Polyhedron, 1999 - Elsevier
… of alkenes to give alcohols and amines respectively. This … of oxygen by bubbling nitrogen
through the solution for 30 … fill cycles of evacuation and nitrogen filling. The solution of alkene in …

CarbonNitrogen Bond Formation via the Vanadium Oxo Catalyzed Sigmatropic Functionalization of Allenols

BM Trost, JS Tracy - Organic letters, 2017 - ACS Publications
… followed by protection of the alcohol to form either 25 or 26. From the protected alcohol,
Magnus’s … functionalization has been used to form carbonnitrogen bonds. Additionally, allenol …