Stereodynamics of acyclic alcohols, ethers, and N, N-dimethylurethanes. Potential barriers to rotation about carbon-carbon and carbon-nitrogen bonds
S Hoogasian, CH Bushweller… - The Journal of …, 1976 - ACS Publications
… the DNMR measurement of the rate of tert-butyl rotation in a series of selectively deuterated
acyclic alcohols, methyl ethers, and urethanes. The tert-butyl rotor was selected in order to …
acyclic alcohols, methyl ethers, and urethanes. The tert-butyl rotor was selected in order to …
Stereocontrolled formation of several carbon–carbon bonds in acyclic systems
G Eppe, D Didier, I Marek - Chemical Reviews, 2015 - ACS Publications
… heteroelements such as oxygen, sulfur, and nitrogen in ortho position could lead to yields up
to … carbon center to give 90 that could be oxidized with retention of configuration into alcohol …
to … carbon center to give 90 that could be oxidized with retention of configuration into alcohol …
Asymmetric reductions of carbon-nitrogen double bonds. A review
QC Zhu, RO Hutchins, MK Hutchins - Organic preparations and …, 1994 - Taylor & Francis
… 2, Reductions of Acyclic [mines A fruitful approach to the synthesis of acyclic 2-amin0
alcohol diastereomers involves reaction of silylether protected cyanohydrins (23) with Grignard …
alcohol diastereomers involves reaction of silylether protected cyanohydrins (23) with Grignard …
Carbon dioxide and molecular nitrogen as switches between ionic and uncharged room-temperature liquids comprised of amidines and chiral amino alcohols
T Yu, T Yamada, GC Gaviola, RG Weiss - Chemistry of Materials, 2008 - ACS Publications
… Neat 1.0 mm path length samples of both with A molecules containing acyclic, saturated
side groups are almost completely transparent above 300 nm (Supporting Information Figure …
side groups are almost completely transparent above 300 nm (Supporting Information Figure …
Asymmetric Ring‐Opening of Cyclopropyl Ketones with Thiol, Alcohol, and Carboxylic Acid Nucleophiles Catalyzed by a Chiral N,N′‐Dioxide–Scandium(III) …
… carbon chains of alcohols had no obvious influence on the enantioselectivities (entries 1–4).
Besides the acyclic substituted alcohols, cyclic substituted alcohols … for 0.5 h under nitrogen …
Besides the acyclic substituted alcohols, cyclic substituted alcohols … for 0.5 h under nitrogen …
… synthesis at nitrogen by oxidation of imines with m-chloroperbenioic acid in the presence of optically active carbinols. Absolute stereochemistry of chiral alcohol-imine …
M Bucciarelli, A Forni, I Moretti, G Torre - Journal of the Chemical …, 1980 - pubs.rsc.org
… alcohols are used as the chiral media; for instance, oxidation of sulphides in the presence of
chiral alcohols … out in the presence of acyclic or cyclic aliphatic alcohols ; the optical purity of …
chiral alcohols … out in the presence of acyclic or cyclic aliphatic alcohols ; the optical purity of …
Chromatographic determination of the absolute configuration of an acyclic secondary alcohol using difluorodinitrobenzene
K Harada, Y Shimizu, A Kawakami… - Analytical …, 2000 - ACS Publications
… substituents of the alcohol and leucinamide moieties, the … applied to various chiral acyclic
secondary alcohols including … the auxiliary and sheath gas nitrogen pressure set at 5 units …
secondary alcohols including … the auxiliary and sheath gas nitrogen pressure set at 5 units …
1, 2-Amino alcohols and their heterocyclic derivatives as chiral auxiliaries in asymmetric synthesis
DJ Ager, I Prakash, DR Schaad - Chemical Reviews, 1996 - ACS Publications
… alcohols provide for nucleophilic substitution under Mitsunobu conditions with the stereochemistry
controlled by the nitrogen … Although not derived from an acyclic amino alcohol, the …
controlled by the nitrogen … Although not derived from an acyclic amino alcohol, the …
Addition of water and ammonia to the carbon–carbon double bond of acyclic alkenes and strained bicyclic dienes; a computational study
HF Koch, LA Girard, DM Roundhill - Polyhedron, 1999 - Elsevier
… of alkenes to give alcohols and amines respectively. This … of oxygen by bubbling nitrogen
through the solution for 30 … fill cycles of evacuation and nitrogen filling. The solution of alkene in …
through the solution for 30 … fill cycles of evacuation and nitrogen filling. The solution of alkene in …
Carbon–Nitrogen Bond Formation via the Vanadium Oxo Catalyzed Sigmatropic Functionalization of Allenols
… followed by protection of the alcohol to form either 25 or 26. From the protected alcohol,
Magnus’s … functionalization has been used to form carbon–nitrogen bonds. Additionally, allenol …
Magnus’s … functionalization has been used to form carbon–nitrogen bonds. Additionally, allenol …
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- carbon nitrogen double bonds
- acyclic alcohols potential barriers
- acyclic systems several carbon
- acyclic systems carbon quaternary stereogenic centers
- chiral amino alcohols molecular nitrogen
- asymmetric reductions carbon nitrogen
- potential barriers carbon nitrogen
- acyclic alkenes carbon double bond
- chiral amino alcohols carbon dioxide