Complex-radical alternating copolymerization

ZMO Rzaev - Progress in Polymer Science, 2000 - Elsevier
… in radical copolymerization, cyclocopolymerization and … of copolymers with alternating
structure are discussed in detail. In this review, new aspects of complex-radical copolymerization

… Cyclocopolymerization of a Transformable Divinyl Monomer with a Monovinyl Monomer and Postpolymerization Modification for the Synthesis of AAB-Type Alternating …

X Xu, M Ouchi - Macromolecules, 2023 - ACS Publications
In this work, we successfully synthesized AAB sequence-controlled copolymers of acrylamide
(A) and vinyl ether (VE, B) via radical cyclocopolymerization of a diacrylate monomer …

Alternating sequence control for carboxylic acid and hydroxy pendant groups by controlled radical cyclopolymerization of a divinyl monomer carrying a cleavable …

M Ouchi, M Nakano, T Nakanishi… - Angewandte Chemie …, 2016 - Wiley Online Library
… : Controlled cyclopolymerization of a hemiacetal ester (HAE) bond-connected divinyl monomer
and subsequent cleavage of the HAE in the cyclo-pendant led to alternating copolymers

Precise Syntheses of Alternating Cyclocopolymers via Radical Copolymerizations of Divinyl Ether with N-Substituted Maleimides

H Kubota, M Ouchi - Macromolecules, 2022 - ACS Publications
alternating cyclocopolymers and multiblock copolymers were successfully synthesized via
free radical copolymerization and RAFT copolymerization … by the copolymerization behaviors, …

Free radical cyclopolymerization: A tool towards sequence control in functional polymers

D Pasini, A Nitti - European Polymer Journal, 2020 - Elsevier
… an alternating copolymer of methacrylic acid and N-isopropyl acrylamide (NIPAM), polymer
P23 in Fig. 8, by selective cyclopolymerization and transformation of the repeating units. …

Control of the Alternating Sequence for N‐Isopropylacrylamide (NIPAM) and Methacrylic Acid Units in a Copolymer by Cyclopolymerization and Transformation of the …

Y Kametani, M Sawamoto, M Ouchi - Angewandte Chemie, 2018 - Wiley Online Library
Cyclopolymerization of 1 was then studied with ruthenium-catalyzed living radical
polymerization. Limited solvents were available to solubilize the resultant cyclopolymer, and …

Unprecedented Sequence Control and Sequence‐Driven Properties in a Series of AB‐Alternating Copolymers Consisting Solely of Acrylamide Units

Y Kametani, F Tournilhac, M Sawamoto… - Angewandte …, 2020 - Wiley Online Library
… to control the alternating sequence in copolymers by selective radical cyclopolymerization
and … of methacrylic acid and N-isopropyl acrylamide by selective cyclopolymerization and side-…

Alternating terpolymers through cyclopolymerization and subsequent orthogonal functionalization

P Gerdt, A Studer - Angewandte Chemie International Edition, 2022 - Wiley Online Library
alternating copolymers by reversible deactivation radical polymerization was developed.
Copolymerization … fluorinated divinyl monomer yields alternating cyclopolymers that can be …

Precision AABB-type cyclocopolymers via alternating cyclocopolymerization of disiloxane-tethered divinyl monomers

J Lu, J Li, J Wang, M Du, H Liu - Polymer Chemistry, 2020 - pubs.rsc.org
… The synthesis of alternating copolymers by radical polymerizations provides a convenient
… Typical alternating copolymers are synthesized via the copolymerization of strongly electron-…

Radical Stitching Polymerization and Its Alternating Copolymerization

Y Hamada, S Togawa, R Shintani - Journal of the American …, 2024 - ACS Publications
… the radical stitching polymerization of dialkenyl ketones, we wondered if alternating stitching
copolymerization … As a relevant process, alternating radical cyclocopolymerization of divinyl …