Donor/Acceptor Properties of Aromatic Molecules in Complex MetalMolecule Interfaces

YL Zhao, W Wang, F Qi, JF Li, G Kuang, RQ Zhang… - Langmuir, 2017 - ACS Publications
… electronic structures of molecules that are subjected to such complex MMI configurations. …
molecules with similar aromatic backbones but different terminal groups. We use a molecular

The activation of aromatic molecules with pentaammineosmium (II)

WD Harman - Chemical reviews, 1997 - ACS Publications
… In many aspects, arenes and aromatic heterocycles are ideal synthons for complex organic
metal systems that are known to form stable η 2 complexes with aromatic molecules, 15-24 …

An All-Metal Aromatic Sandwich Complex [Sb3Au3Sb3]3–

FX Pan, LJ Li, YJ Wang, JC Guo, HJ Zhai… - Journal of the …, 2015 - ACS Publications
metal sandwich complex, in which a metal center or metal sheet is jammed between two
aromatic metal rings, has not been isolated, although a large amount of molecules such as [Al 4 …

The chemistry of aromatic osmacycles

XY Cao, Q Zhao, Z Lin, H Xia - Accounts of Chemical Research, 2014 - ACS Publications
… -metal fragment. Researchers have studied these transition-metal-containing aromatic
molecules … to metallabenzenes, starting from a metal complex and a commercially available C 5 …

Stacking interactions of aromatic ligands in transition metal complexes

DP Malenov, SD Zarić - Coordination Chemistry Reviews, 2020 - Elsevier
… This geometry is particularly important because molecular recognition processes start at …
interaction between coordinated benzene of one complex and metal of the other complex (be). …

Structure and bonding of large aromatic molecules on noble metal surfaces: The example of PTCDA

FS Tautz - Progress in Surface Science, 2007 - Elsevier
… states of the molecule and the metal are involved in the bond? What is the exact structure
of the adsorbate–substrate complex (adsorption site, vertical distance, molecular distortions, …

Metal Ion-Aromatic Complexes. III. The Crystal and Molecular Structure of C6H6·CuAlCl4

RW Turner, EL Amma - Journal of the American Chemical Society, 1966 - ACS Publications
… three metal-to-chlorine bonds and one -type metal ion-aromatic … anions play an important
role in the stability of this complex. … are examining a number of metal-ion aromatic complexes. A …

High-Resolution Electron Spectroscopy of Gas-Phase MetalAromatic Complexes

DS Yang - The Journal of Physical Chemistry Letters, 2011 - ACS Publications
… Because the IE of a metal atom is generally lower than that of an organic molecule,
ionization of a metal complex removes a metal-based electron and affects mostly metal−ligand …

Intramolecular aromatic substitution in transition metal complexes

GW Parshall - Accounts of Chemical Research, 1970 - ACS Publications
… ligand moleculearomatic substitutions than that proposed for the Ru complex. The reversible
loss of H2 (step E) from the ruthenium compound is a common reaction of transition metal

Advances in metal chemistry of quinonoid compounds: new types of interactions between metals and aromatics

A Vigalok, D Milstein - Accounts of Chemical Research, 2001 - ACS Publications
… both the metal center and the carbonyl part of the molecule, … metal−benzyl complex with an
oxy group in the para position. Electron transfer from the oxygen to the metal via the aromatic