TEMPO-catalyzed oxidative dimerization and cyanation of indoles for the synthesis of 2-(1H-indol-3-yl)-3-oxoindoline-2-carbonitriles

L Jiang, X Peng, P Huang, Z Chen, L Liu - Tetrahedron, 2017 - Elsevier
… of indoles. Notably, Shen and co-workers developed a catalytic tandem cyanation of indoles
… TEMPO-catalyzed oxidative homo dimerization and cyanation of free indole derivatives for …

A Review on Thiocyanation of Indoles

C Divyavani, P Padmaja, VG Ugale… - Current Organic …, 2021 - ingentaconnect.com
… This section provides an account of different methods on thiocyanation of indoles. … that
SCNis oxidized via a one-electron oxidation process to a radical, which undergoes dimerization at …

A multifunctionalized strategy of indoles to C2-quaternary indolin-3-ones via a TEMPO/Pd-catalyzed cascade process

Z Deng, X Peng, P Huang, L Jiang, D Ye… - Organic & Biomolecular …, 2017 - pubs.rsc.org
… /Pd-catalyzed oxidative homo dimerization and cyanomethylation of free indole derivatives
for … Notably, Shen and co-workers developed the catalytic tandem cyanation of indoles with …

Aerobic oxidative functionalization of indoles

S Liu, F Zhao, X Chen, GJ Deng… - Advanced Synthesis & …, 2020 - Wiley Online Library
… aerobic oxidation modes, a range of functionalized indole … of indoles leads to indole
alkenylation, arylation, cyanation, … workers optimized the dimerization of indole to afford …

Recent advances in C–CN and C–H bond activation of green nitrile (MeCN) for organo-complexation, cyanation and cyanomethylation

MS Ahmad, IN Pulidindi, C Li - New Journal of Chemistry, 2020 - pubs.rsc.org
… Similarly, our group reported a new way for the selective cyanation of indoles with a Cu-…
Another combinative oxidative system for cyanomethylation and homo dimerization of indole

[HTML][HTML] Palladium-catalyzed late-stage direct arene cyanation

D Zhao, P Xu, T Ritter - Chem, 2019 - cell.com
… as indoles, which limit their synthetic applications. Here we describe an undirected,
palladium-catalyzed late-stage aryl C–H cyanation … (III)-mediated oxidative cyanation of …

Palladium catalyzed nitrile insertion and cyanation of biindoles: Synthesis of indole fused α-carboline scaffolds via double C–H activation

A Kalyani, RNP Tulichala, S Chauhan, KCK Swamy - Tetrahedron Letters, 2022 - Elsevier
… 2 as the oxidant and only traces of product 3aa was formed using Cu(OTf) 2 . Use of AgOAc
or Ag 2 O as an oxidant … to afford cyanation at the 3′-position of one of the indole moieties. …

Carbonylated Indoles from PdII-Catalyzed Intermolecular Reactions of Indolyl Cores

J Le Bras, J Muzart - Synthesis, 2019 - thieme-connect.com
… [73] This intriguing cyanation has been studied in detail by … a mechanism preserving the
initial oxidation state of palladium … leads to indole-2-carbothioamide 60 E, which is oxidized with …

Recent studies of bifunctionalization of simple indoles

ZY Wang, S Xu, KK Wang, N Kong… - Asian Journal of Organic …, 2021 - Wiley Online Library
… Liu and co-workers 32d elaborated a TEMPO-catalyzed oxidative dimerization and cyanation.
… 31c, 32b, 32e were widely used in these oxidative dimerization of indoles (Scheme 36). …

[PDF][PDF] A brief on thiocyanation of N-activated arenes and N-bearing heteroaromatic compounds

K Nikoofar - Chem. Sci. Trans.–2013, 2013 - e-journals.in
… -free source for the cyanation of arylboronic acids to nitriles12. … and dimerization of the
substrate occurred56 (Scheme 8). … So oxone oxidized indole rather than ammonium thiocyanate …