Complexes of diamagnetic cations with radical anion ligands

IV Ershova, AV Piskunov… - Russian Chemical …, 2020 - iopscience.iop.org
… Meanwhile, before this review, no attempts were made to integrate and systematize the
existing data on the nature of magnetic exchange between the radical redox-active ligands …

Magnetic Interactions Mediated by Diamagnetic Cations in [Mn18M] (M = Sr2+, Y3+, Cd2+, and Lu3+) Coordination Clusters

AM Ako, B Burger, Y Lan, V Mereacre… - Inorganic …, 2013 - ACS Publications
… The crystal structures were directly employed for the calculations considering the presence
of eight azido ligands coordinated to the Mn III cations. The calculated J values were …

Enhancement of magnetic relaxation properties with 3d diamagnetic cations in [Zn II Ln III] and [Ni II Ln III], Ln III= Kramers lanthanides

J Mayans, Q Saez, M Font-Bardia, A Escuer - Dalton Transactions, 2019 - pubs.rsc.org
… a diamagnetic divalent 3d cation using compartmental ligands, 15 which is one of the best
ways to control the number and nature of metal ions in the same molecule. There is a wide …

Mapping the Binding Modes of Hemilabile Pincer–Crown Ether Ligands in Solution Using Diamagnetic Anisotropic Effects on NMR Chemical Shift

AM Camp, MR Kita, J Grajeda, PS White… - Inorganic …, 2017 - ACS Publications
… , pentadentate-bound cation 1 and tetradentate-bound carbonyl cation 8 were fully assigned…
The significant Δδ values may originate from oxygen diamagnetic anisotropy from the ethers …

Diamagnetic corrections and Pascal's constants

GA Bain, JF Berry - Journal of Chemical Education, 2008 - ACS Publications
… Specifically, Table 6 contains χDi values for cations assuming … For diamagnetic molecules
or ligands in routine use, the … at room temperature for two common ligands listed in Table 4, 2,2…

Proton chemical shifts and diamagnetic anisotropy in cobalt (III) pentaammine complexes

R Bramley, II Creaser, DJ Mackey… - Inorganic …, 1978 - ACS Publications
… is even worse for the extended series of X ligands we have studied, which includes F" and
… Using the field effect coefficient given in ref 18 and the known cation geometry, we calculate …

Molecular and Electronic Structures of Bis-(o-diiminobenzosemiquinonato)metal(II) Complexes (Ni, Pd, Pt), Their Monocations and -Anions, and of Dimeric Dications …

D Herebian, E Bothe, F Neese… - Journal of the …, 2003 - ACS Publications
… the electronic structures of these cations and anions and to resolve … can dimerize in solution
yielding diamagnetic dimers [M II (L … that air oxidation of a mixture of the ligand H 2 [ 2 L PDI ]·…

Searching for switchable molecular conductors: Salts of [M (dcbdt) 2](M= Ni, Au) anions with [Fe (sal2-trien)]+ and [Fe (phen) 3] 2+

LCJ Pereira, AM Gulamhussen, JC Dias… - Inorganica Chimica …, 2007 - Elsevier
cations such as [Fe(sal 2 -trien)] + (sal 2 -trien is the ligand … to result from contributions of
the cation, which a priory can be … S = 1/2 Ni anion, while the Au anion is diamagnetic. The χT …

Ambient temperature anion-dependent spin state switching observed in “mostly low spin” heteroleptic iron (II) diimine complexes

Z Ni, AM McDaniel, MP Shores - Chemical Science, 2010 - pubs.rsc.org
… Fe II ligand field parameters and anioncation interactions as … field ligands into the complex
architecture gives rise to anion-… In contrast to diamagnetic hosts, we find that subtle spin state …

… dimeric Ni (II) complex anion and its counter cationic monomeric Ni (II) complex, and some other mononuclear transition metal compounds using some neutral ligands

B Biswas, A Pal, GR Krishna, CM Reddy, F Tuna… - Polyhedron, 2011 - Elsevier
… The trinuclear nickel(II) complex 3 is made of a dinuclear anion and a mononuclear cation. …
corrected for diamagnetism by using Pascal constants, and for the diamagnetic contribution …