Chemistry of 2-alkoxy-3, 4-dihydro-2H-pyrans. II. Addition of dimethyl acetylenedicarboxylate to 2-alkoxy-6-methyl-3, 4-dihydro-2H-pyrans

SS Hall, AJ Duggan - The Journal of Organic Chemistry, 1974 - ACS Publications
… ,4-dihydro-2ff -pyran (1) and 2alkoxy-3,4-dihydro-2H-pyrans … dimethyl acetylenedicarboxylate.
Refluxing a toluene solution of 2-methoxy-6-methyl-3,4dihydro-2ff-pyran (3a) and dimethyl

… 1H)-ones and 3,4-Dihydro-2H-pyrans via Four-Component Reactions of Aromatic Aldehydes, Cyclic 1,3-Carbonyls, Arylamines, and Dimethyl Acetylenedicarboxylate

J Sun, EY Xia, Q Wu, CG Yan - ACS Combinatorial Science, 2011 - ACS Publications
… 3,4-dihydro-2H-pyrans via four-component reactions of arylamines, acetylenedicarboxylate,
… reaction of arylamine with dimethyl acetylenedicarboxylate to arylidine cyclic 1,3-diketones. …

Novel heterocyclization of hydrazinopyridazinones with dimethyl acetylenedicarboxylate with dehydrogenation and rearrangement

T Yamasaki, E Kawaminami, T Yamada… - Journal of the …, 1991 - pubs.rsc.org
… 5- Hydrazinopyridazin-3(2H) -ones 1 reacted with dimethyl acetylenedicarboxylate 2 to give
4,6dihydropyridazino[4,5-c] pyridazin-5- (1 H) -ones 3 by cyclization with dehydrogenation. …

Reaction of dimethyl acetylenedicarboxylate with 2-ethyl-3-phenyl-2H-5, 6-dihydro-1, 2-oxazine

I Goldberg, D Saad, E Shalom… - The Journal of Organic …, 1982 - ACS Publications
Reaction of dimethyl acetylenedicarboxylate with 2-ethyl-3-phenyl-2H-5,6-dihydro-1,2-…
and Gygax found that the ammonium ion 3-cyclohexyl-l,6dimethyl-2-oxa-3-azoniabicyclo[4.4.0]…

Reaction of dimethyl acetylenedicarboxylate with 3, 4-disubstituted isoxazolin-5-ones. A new synthesis of 1, 3-oxazin-6-ones and 2, 3-dihydro-1, 3-oxazin-6-ones

EM Beccalli, A Marchesini, ML Gelmi… - The Journal of Organic …, 1987 - ACS Publications
… We have now found that the title compounds 1 react with 0.5 mol of dimethyl
acetylenedicarboxylate (DMAD), in the presence of a base to give the (2,3-dihydro-l,3-oxazin-6-ones) …

Cycloaddition reactions of indenes. 2. Reactions with dimethyl acetylenedicarboxylate and maleic anhydride

WE Noland, V Kameswaran… - The Journal of Organic …, 1980 - ACS Publications
… 1H-Indenes (1) react with dimethyl acetylenedicarboxylate (DMAD), unlike maleic anhydride
and other ethylenic dienophiles, without prior isomerizationto 2/f-indenes (2), giving a 1:1 …

Formation of Unusual Products from the Acid‐Catalyzed Reaction of Azulenes with Dimethyl Acetylenedicarboxylate

P Brügger, P Uebelhart, RW Kunz, R Sigrist… - Helvetica chimica …, 1998 - Wiley Online Library
… The reaction of guaiazulene (4) and dimethyl acetylenedicarboxylate (ADM) in tetralin or …
5), the major part of which is derived from dimethyl 2a,4a-dihydrocyclopent[cd]azulene-3,4-…

Reaction between 3 H-pyrrolizines and acetylenedicarboxylic esters. Part I. Preparation of 3-(alkoxycarbonylmethylene)-3 H-pyrrolizines

D Johnson, G Jones - Journal of the Chemical Society, Perkin …, 1972 - pubs.rsc.org
dimethyl acetylenedicarboxylate to give a dihydrocycl- [3,2,2]azine (dimethyl 5,6-dihydro-5,5…
During these experiments we discovered that 3H-pyrrolizine and acetylenedicarboxylic

Reactions of dimethyl acetylenedicarboxylate—VI: Reaction with aldehyde and ketone phenylhydrazones

MK Saxena, MN Gudi, MV George - Tetrahedron, 1973 - Elsevier
… with dimethyl acetylenedicarboxylate gives dimethyl 1,3-… of dimethyl 1,3-diphenylpyrazoline-4,5-dicarboxylate
and … the nucleophilic addition to dimethyl acetylenedicarboxylate, …

The reactivity of 2-vinylindoles with dimethyl acetylenedicarboxylate

RA Jones, PM Fresneda, TA Saliente, JS Arques - Tetrahedron, 1984 - Elsevier
… Abstract - The overall rates of reaction of l-substltuted-l(1-methyl-2-1ndolyl)ethenes with
dimethyl acetylenedicarboxylate … reaction of the system with dimethyl acetylenedicarboxylate, …