… nickel bis(diphosphine) catalysts that contain ligands that are … 1 for electrocatalytic hydrogen
production with overpotentials … two seven-membered cyclic diphosphine ligands 7P Ph 2 N …

… N 2 ligand, a tetradentate phosphine ligand with two pendant amines in the ligand
backbone… an electrocatalyst for the reduction of protons to hydrogen. Using N,N-dimethylformamidium …

… bdt, a chelating phosphine, and a single CO ligand that have proven, in some cases, to
produce hydrogen from … (33-35) We have also shown that the sterically restrictive ligand 1,1′-bis(…

… Studies of those features controlling the hydride acceptor abilities of metal complexes
containing diphosphine ligands have also been carried out in our laboratories. Efforts to match the …

… A Ni-based electrocatalyst for H 2 production, [Ni(8P Ph 2 N C 6 H 4 Br ) 2 ](BF 4 ) 2 ,
featuring eight-membered cyclic diphosphine ligands incorporating a single amine base, 1-para-…

… This small but significant modification of the structure of the diphosphine ligand greatly
improved the catalytic activity of the nickel complex 5 for electrocatalytic H 2 production. The TOF …

… the phosphine ligand in the catalyst system (Figure 8). A mixture of the phosphine ligand and
… We observed the same 31 P signal in a reaction of the phosphine ligand and Fe 3 (CO) 12 …

… The obtained k r values are typical of heteroleptic copper complexes with phenanthroline
and diphosphine ligands.21 Conversely, the obtained k nr values are up to three orders of …

… As a consequence of the high covalency of the Fe–H bond, the electronic properties are
strongly affected by the variation of the donor ability of the diphosphine ligand. …

… Different support materials as well as rhodium(I) complexes with different combinations of
phosphine ligands and counter ions were tested. Complex 11 [Rh(trop 2 N){P(4-nBuPh) 3 }][…