A comparison of some aspects of the aqueous coordination chemistry of aluminum (III) and iron (III)

AL Crumbliss, JM Garrison - Comments on Inorganic Chemistry, 1988 - Taylor & Francis
… The differences in electronegativities (xm), ionic radii (r,) and electron configuration (… structure
and reactivity, hydrolysis, and metal complex stability. Similarities in coordination chemistry

Distinctive coordination chemistry and biological significance of complexes with macrocyclic ligands

DH Busch - Accounts of Chemical Research, 1978 - ACS Publications
… There are probably relatively few reactions in coordination chemistry so well studied as the
… states for these reactions. The cis effect observed in studies on the electronic spectra of frarcs-…

[图书][B] Shriver and Atkins' inorganic chemistry

P Atkins - 2010 - books.google.com
… they can be completed using any electronic structure programme that allows Hartree-Fock, …
of chemical reactions Video clips showing demonstrations of inorganic chemistry reactions

A coordination chemistry approach towards ternary M/14/16 anions

S Dehnen, M Melullis - Coordination chemistry reviews, 2007 - Elsevier
… As an efficient alternative, we have developed a coordination chemical route by using a
preformed binary 14/16 source: by reactions of ortho-chalcogenotetrelate anions [E′E 4 ] 4− …

Ligand influences on structure and reactivity in organoalkaline earth chemistry

TP Hanusa - Chemical reviews, 1993 - ACS Publications
… The lack of ligand control, however, has hindered development of the coordination chemistry
of the heavier alkali and alkaline-earth metals. This situation is now rapidly changing, …

New insights into the electronic structure and reactivity of one-electron oxidized copper (II)-(disalicylidene) diamine complexes

K Asami, K Tsukidate, S Iwatsuki, F Tani… - … chemistry, 2012 - ACS Publications
… a subtle change of electronic structure can have a significant … on the electronic structure of
one-electron oxidized group 10 … subtle differences in electronic structure and interaction with …

Coordination chemistry of metal alkynyl compounds

R Nast - Coordination Chemistry Reviews, 1982 - Elsevier
… their protolysis seems to depend on the electron configuration of the central metal atom. The
… and non-explosive coordination compounds are considerably less reactive than the anionic …

To be or not to be NO in coordination chemistry? A mechanistic approach

M Wolak, R van Eldik - Coordination chemistry reviews, 2002 - Elsevier
… species in solution and the nature of the coordinated ligand. In the present review, reactions
… of NO to the parent metalloporphyrins induces a low spin electronic configuration of the …

Electronic Structure and Reactivity of Isomeric Oxo-Mn(V) Porphyrins:  Effects of Spin-State Crossing and pKa Modulation

F De Angelis, N Jin, R Car, JT Groves - Inorganic chemistry, 2006 - ACS Publications
reactivity should contribute to the higher effective reactivity of the 4-TMPyP species. In the
following, we report detailed electronic structure calculations that strongly support this view. …

Effect of imidazole and phenolate axial ligands on the electronic structure and reactivity of oxoiron (IV) porphyrin π-cation radical complexes: drastic increase in oxo …

A Takahashi, T Kurahashi, H Fujii - Inorganic chemistry, 2009 - ACS Publications
… modulates the electronic structure and reactivity of compound I. The electron paramagnetic
… the axial ligand effect on the electronic structure and reactivity of compound I, it is unclear …