… exocyclic enol ethers are readily available in a stereocontrolled manner,1 the stereoselective
synthesis of enol ethers of type 1 still remains a challenging problem in organic synthesis. …

… stereoselective synthesis can be challenging. Herein, we report a new stereoselective
synthesis of vinyl, aryl, alkynyl, alkyl and thio-substituted Z-enamides and enol ethers based on …

… of primary and secondary allyl ethers in high yields. The primary allyl … ethers produced (E)-enol
ethers and the secondary allyl ethers afforded (Z)-enol ethers with high stereoselectivity…

… ,3,4,4,4-nonafluorobutanesulfonic acid enol esters (hereafter … flask procedure starting from
trimethylsilyl enol ethers,5b has … our studies on their synthesis with silyl enol ethers as starting …

… radicals, to the electron-rich double bond of enol ethers has not been widely studied. This is
… and diethyl thiophosphite to various enol ethers, including enol ethers with unsaturated side …

… efficient strategy for the synthesis of silyl enol ethers with high … silyl enol ethers have been
widely used in organic synthesis, … of silyl enol ethers, trisubstituted silyl enol ethers bearing an …

… enol ethers are very useful compounds in organic synthesis, … reported a stereoselective
synthesis of silyl enol ethers using, … less highly substituted silyl enol ether of some unsymmetrical …

… (d-galactal, 9), underwent stereoselectively a ring contraction by treatment with thallium(III) …
–NaBH 4 reagent in MeOH, providing the enantiomerically pure methyl enol-ethers 3,4,6-tri-O-…

… : Less highly substituted silyl enol ethers are regiospecifically … In addition, a high E-enolization
stereoselectivity is observed … providing the corresponding silyl enol ethers, in three hours, …

… 997 Abstract: We have developed a stereoselective route to 13-hydroxycyclohexanones …
of acyclic enol ethers and an intramolecular aldol reaction. The stereoselectivity of the acid-…