… Recently, the enzymatic defluorination of fluorine-containing compounds has gained …
enzymatic defluorination reactions of fluorinated compounds. Furthermore, we review the enzyme …

… We expect more defluorination activity to be reported among these enzyme families … the
defluorination activity of other known enzymes and identifying putative novel enzymes capable of …

… they defended that this interconversion could be misleading and could be attributed to a
small degree of microbial defluorination of both compounds. This resulted in the liberation of …

… −enzyme covalent intermediate, and enzyme−product complex. We demonstrate that enzymatic
defluorination … the fluoride ion but also is finely tailored for the smaller fluorine halogen …

… enzymatic defluorination, we examined a defluorination reaction that could be catalyzed by
either sodium hydroxide or the enzyme … , which allows for defluorination of fluoroatrazine to …

… differs from other halogens and so we would anticipate that many dechlorinating enzymes
would fail to catalyze defluorination of analogous molecules. Exceptions are known with some …

… defluorination in the vicinity of a heme group may generate a stable iron(III)-fluoride complex,
potentially leading to enzyme … of oxidative defluorination by P450 enzymes we decided to …

… Fluoroacetate is readily metabolized in rats (2,4,8) and undergoes defluorination by liver
enzymes in the presence of GSH1 (9-13). The present study makes novel use of 19F and 13C …

… , and an observable fluoride concentration increase was … This suggests potential activity
of a dehalogenase enzyme … enzymes have shown potential for enzymatic defluorination, …

… the catalytic center of defluorinating enzymes, which may or … the responsible defluorinating
enzymes/microorganisms are … reductive defluorination of >C 2 perfluorinated compounds …