Diastereoselective synthesis of steroid–[60] fullerene hybrids and theoretical underpinning

D Alonso, D Hernández-Castillo… - The Journal of …, 2020 - ACS Publications
… ]fullerene hybrids, in this work we report the synthesis of novel steroid–[60]fullerene hybrids
via … , (23) so its condensation with fullerene could give rise to hybrids with promising potential …

Templated regioselective and stereoselective synthesis in fullerene chemistry

F Diederich, R Kessinger - Accounts of chemical research, 1999 - ACS Publications
… Compounds 24 (MW = 5317) and 25 (MW = 7086) are solubilized derivatives of C 195 and
C 260 , two members of a new class of fullerene−acetylene hybrid carbon allotropes with the …

Diastereoselective Synthesis of C60/Steroid Conjugates

A Ruiz, J Coro, L Almagro, JA Ruiz… - The Journal of …, 2013 - ACS Publications
… Continuing our research on the synthesis of new functionalized steroid–fullerene hybrids,
in this paper we have chosen an important steroid to be used as steroid moiety, namely …

Catalytic stereodivergent synthesis of steroid–fulleropyrrolidine hybrids

M Suárez, A Ruiz, L Almagro, J Coro… - The Journal of …, 2017 - ACS Publications
… With the aim to prepare steroid–fullerene hybrids with a controlled stereochemistry, here
we report on the stereoselective 1,3-dipolar cycloaddition of steroid N-metalated azometine …

Stereodivergent‐at‐metal synthesis of [60] fullerene hybrids

J Marco‐Martínez, S Vidal, I Fernández… - Angewandte Chemie …, 2017 - Wiley Online Library
synthesis is based on enantioselective synthesis of suitably functionalized pyrrolidino[60]fullerenes
and further diastereoselective … employed and the diastereoselective addition of the …

Steroid–fullerene hybrids from epiandrosterone: synthesis, characterization and theoretical study

L Almagro, D Hernández‐Castillo… - European Journal of …, 2018 - Wiley Online Library
… using steroid templates afforded regio- and stereoselective bis-adducts.28 Actually, a …
chemistry of fullerene hybrids, here we report on the design of new steroid–fullerene hybrids using …

Bisaziridine Tetracarboxylates as Building Blocks in the Stereoselective Synthesis of C60-Fullerene Diads and Dumbbell-like Bis-C60-fullerene Triads

AS Konev, AF Khlebnikov… - The Journal of Organic …, 2011 - ACS Publications
… The reaction of azomethine ylides derived from the bisaziridines with fullerene C 60 was
optimized and used for the stereoselective preparation of both the monoadducts (C 60 –linker–…

Steroid-fullerene hybrids: a review

M Ibrahim-Ouali, F Dumur - ARKIVOC-Online Journal of Organic …, 2022 - hal.science
… This is an efficient stereodivergent protocol to synthesize hybrid systems in a
diastereoselective manner allowing access to a variety of optically active fullerene hybrids. …

Dumbbell-Type Fullerene-Steroid Hybrids: A Join Experimental and Theoretical Investigation for Conformational, Configurational, and Circular Dichroism Assignments

A Ruiz, C Morera-Boado, L Almagro… - The Journal of …, 2014 - ACS Publications
… We have previously reported hybrid fullerene-steroid … (8) More recently, a diastereoselective
synthesis of C 60 -… of a fullerene hybrid dumbbell endowed with two fullerene units …

Stereoselective synthesis on fullerenes: properties and photoelectrochemical applications

RM Girón Rubio - 2019 - docta.ucm.es
… New chiral fullerenes derivatives endowed with metal centers have been prepared and
we have achieved the first stereoselective synthesis of gold(I)fullerene hybrids. …