Functional Chimeras: New Bingel–HirschType Steroid–Fullerene Hybrids

J Coro, H Rodriguez, DG Rivera, M Suarez, D Molero… - 2009 - Wiley Online Library
fullerene hybrids, here we report on the design of a new type of molecular chimeras
produced by conjugation of naturally occurring steroids to fullerene by the so-called Bingel–Hirsch

Spherical aromaticity of fullerenes

M Bühl, A Hirsch - Chemical Reviews, 2001 - ACS Publications
… standard hybridization theory. The POAV2 analysis defines a π orbital to be the hybrid orbital
… It allows the fractional hybridization (m/m +1) of the atomic π orbitals (s m p) obtained from …

Covalent inter-synthetic-carbon-allotrope hybrids

T Wei, F Hauke, H Andreas - Accounts of Chemical Research, 2019 - ACS Publications
… Following this strategy, we covalently constructed the first CNT-endohedral fullerene hybrid
by employing endohedral Sc 3 N@C 80 as a spherical building block (Scheme 5). (32) To …

Morphological behavior of fullerene‐steroid hybrid derivatives

R Lemos, F Ortiz, L Almagro… - Surface and …, 2022 - Wiley Online Library
… [60]fullerene derivatives were prepared by a Bingel–Hirsch-… [60]fullerene cage through
a Bingel–Hirsch reaction in a … , we synthesized some of the hybrids previously reported (Ib-…

Hybrid Steroid‐[60] Fullerene as n‐Type Material for Organic Photovoltaics

R Lemos, Y Perez‐Badell, O Ortiz… - European Journal of …, 2024 - Wiley Online Library
… In this work, a steroid-fullerene hybrid was synthesized through the Bingel–Hirsch reaction
to compare its properties with PC61BM as the reference structure. Different spectroscopic …

Hybrids of fullerenes and 2D nanomaterials

M Chen, R Guan, S Yang - Advanced Science, 2019 - Wiley Online Library
… review of all types of hybrids of fullerenes and 2D … fullerene-2D nanomaterial hybrids,
especially the opportunity of creating unknown functional materials by means of hybridization

Dumbbell-Type Fullerene-Steroid Hybrids: A Join Experimental and Theoretical Investigation for Conformational, Configurational, and Circular Dichroism Assignments

A Ruiz, C Morera-Boado, L Almagro… - The Journal of …, 2014 - ACS Publications
… We have previously reported hybrid fullerene-steroid derivatives prepared by Bingel–Hirsch
preparation of a fullerene hybrid dumbbell endowed with two fullerene units connected …

Endohedral and exohedral hybrids involving fullerenes and carbon nanotubes

M Vizuete, M Barrejón, MJ Gómez-Escalonilla, F Langa - Nanoscale, 2012 - pubs.rsc.org
… the CNT and both types of hybrid have specific features. CNT–fullerene hybrids have been
studied for … This review outlines the progress in research on CNT–fullerene hybrids, including …

Synthesis and atropisomerism of cascaded tetraphenylporphyrin–[60] fullerene hybrids

S Schlundt, W Bauer, A Hirsch - Chemistry–A European …, 2015 - Wiley Online Library
… –fullerene dyads,10, 11 water-soluble dyads,12–14 and dendritic TPP–fullerene conjugates
… of our previously reported dendritic TPP–[60]fullerene hybrid 115 (Figure 1) by ferrocene, …

Steroid–fullerene hybrids from epiandrosterone: synthesis, characterization and theoretical study

L Almagro, D Hernández‐Castillo… - European Journal of …, 2018 - Wiley Online Library
… the chemistry of fullerene hybrids, here we report on the design of new steroid–fullerene
hybrids using the … Using the Bingel–Hirsch protocol, we describe new mono-adducts steroid-[60]…