Effect of interfacial energetics on dispersion and glass transition temperature in polymer nanocomposites

B Natarajan, Y Li, H Deng, LC Brinson… - …, 2013 - ACS Publications
… Developing structure–property relationships between the filler/matrix interface chemistry
and the dispersion and interface properties of polymer nanocomposites (PNC) is critical to …

Effect of interface on bulk polymer: control of glass transition temperature of rubber

Y Wei, H Wu, G Weng, Y Zhang, X Cao, Z Gu… - Journal of Polymer …, 2018 - Springer
… and glass transition of rubber can be controlled by constructing attractive interface between
… that interfacial segmental mobility was reduced and glass transition temperatures (T g s) of …

Interface and surface effects on the glass-transition temperature in thin polymer films

AL Richard - Faraday Discussions, 1994 - pubs.rsc.org
… of polymers at surfaces and interfaces, there has been much … polymer mobility at an interface,
control many technologically … the effects of surfaces and interfaces on the glass transition, …

Effect of interfaces on the glass transition of supported and freestanding polymer thin films

RP White, CC Price, JEG Lipson - Macromolecules, 2015 - ACS Publications
… We investigate the glass transition behavior in polymer thin films using a model equation-of-state
approach, which involves molecular parameters whose values are determined from fits …

Interface and chain confinement effects on the glass transition temperature of thin polymer films

JA Forrest, K Dalnoki-Veress, JR Dutcher - Physical Review E, 1997 - APS
… ellipsometry to measure the glass transition temperature Tg of … of chain confinement effects
on the glass transition temperature of … is the dominant effect in determining the glass transition

Glass transition of polymers in bulk, confined geometries, and near interfaces

S Napolitano, E Glynos, NB Tito - Reports on Progress in Physics, 2017 - iopscience.iop.org
… through the phenomenology and salient theories of the glass transition (1). We then focus
on operational definitions of the glass transition temperature in experiments and in silico, on …

Glass transition of stereoregular poly (methyl methacrylate) at interfaces

Y Grohens, M Brogly, C Labbe, MO David, J Schultz - Langmuir, 1998 - ACS Publications
… Up to now, the real nature of the glass transition process, … This transition has often been
discussed through theories mainly … , the effects of a surface or an interface on the glass transition

Influence of an impenetrable interface on a polymer glass-transition temperature

WE Wallace, JH van Zanten, WL Wu - Physical review E, 1995 - APS
… show no glass transition up to at least 60 'C above the bulk glass-transition temperature,
while a break in the thickness versus temperature curve, signaling the glass transition and the …

Effect of interfacial interactions on the glass transition of polymer thin films

OKC Tsui, TP Russell, CJ Hawker - Macromolecules, 2001 - ACS Publications
… to distinguish between effects at either surface. The bilayer model discussed above essentially
describes the combined effects of the air and the substrate interfaces, parametrized by …

Reduced glass transition temperatures in thin polymer films: Surface effect or artifact?

O Bäumchen, JD McGraw, JA Forrest… - Physical Review Letters, 2012 - APS
… This trend is observed in all cases and we find that the reduced glass transitions of films
with two free interfaces are characterized by a slope-melt contrast of 1:4 Æ 0:3 and for the …