Effect of interfacial energetics on dispersion and glass transition temperature in polymer nanocomposites
… Developing structure–property relationships between the filler/matrix interface chemistry
and the dispersion and interface properties of polymer nanocomposites (PNC) is critical to …
and the dispersion and interface properties of polymer nanocomposites (PNC) is critical to …
Effect of interface on bulk polymer: control of glass transition temperature of rubber
Y Wei, H Wu, G Weng, Y Zhang, X Cao, Z Gu… - Journal of Polymer …, 2018 - Springer
… and glass transition of rubber can be controlled by constructing attractive interface between
… that interfacial segmental mobility was reduced and glass transition temperatures (T g s) of …
… that interfacial segmental mobility was reduced and glass transition temperatures (T g s) of …
Interface and surface effects on the glass-transition temperature in thin polymer films
AL Richard - Faraday Discussions, 1994 - pubs.rsc.org
… of polymers at surfaces and interfaces, there has been much … polymer mobility at an interface,
control many technologically … the effects of surfaces and interfaces on the glass transition, …
control many technologically … the effects of surfaces and interfaces on the glass transition, …
Effect of interfaces on the glass transition of supported and freestanding polymer thin films
RP White, CC Price, JEG Lipson - Macromolecules, 2015 - ACS Publications
… We investigate the glass transition behavior in polymer thin films using a model equation-of-state
approach, which involves molecular parameters whose values are determined from fits …
approach, which involves molecular parameters whose values are determined from fits …
Interface and chain confinement effects on the glass transition temperature of thin polymer films
… ellipsometry to measure the glass transition temperature Tg of … of chain confinement effects
on the glass transition temperature of … is the dominant effect in determining the glass transition …
on the glass transition temperature of … is the dominant effect in determining the glass transition …
Glass transition of polymers in bulk, confined geometries, and near interfaces
… through the phenomenology and salient theories of the glass transition (1). We then focus
on operational definitions of the glass transition temperature in experiments and in silico, on …
on operational definitions of the glass transition temperature in experiments and in silico, on …
Glass transition of stereoregular poly (methyl methacrylate) at interfaces
… Up to now, the real nature of the glass transition process, … This transition has often been
discussed through theories mainly … , the effects of a surface or an interface on the glass transition …
discussed through theories mainly … , the effects of a surface or an interface on the glass transition …
Influence of an impenetrable interface on a polymer glass-transition temperature
WE Wallace, JH van Zanten, WL Wu - Physical review E, 1995 - APS
… show no glass transition up to at least 60 'C above the bulk glass-transition temperature,
while a break in the thickness versus temperature curve, signaling the glass transition and the …
while a break in the thickness versus temperature curve, signaling the glass transition and the …
Effect of interfacial interactions on the glass transition of polymer thin films
… to distinguish between effects at either surface. The bilayer model discussed above essentially
describes the combined effects of the air and the substrate interfaces, parametrized by …
describes the combined effects of the air and the substrate interfaces, parametrized by …
Reduced glass transition temperatures in thin polymer films: Surface effect or artifact?
… This trend is observed in all cases and we find that the reduced glass transitions of films
with two free interfaces are characterized by a slope-melt contrast of 1:4 Æ 0:3 and for the …
with two free interfaces are characterized by a slope-melt contrast of 1:4 Æ 0:3 and for the …
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