Principles of chemical bonding and band gap engineering in hybrid organic–inorganic halide perovskites

A Walsh - The Journal of Physical Chemistry C, 2015 - ACS Publications
… solar cells based on hybrid halide perovskites has seen an … : a semiconductor with an optical
band gap in the optimal region of … chemical bonding of hybrid perovskites is discussed here, …

Steric engineering of metal-halide perovskites with tunable optical band gaps

MR Filip, GE Eperon, HJ Snaith, F Giustino - Nature communications, 2014 - nature.com
band gap of metal-halide perovskites, a key design parameter for solar cells, strongly correlates
with a simple structural feature, the largest metal–halide–… Precise band gap engineering

Bandgap engineering of lead-free ternary halide perovskites for photovoltaics and beyond: Recent progress and future prospects

U Farooq, M Ishaq, UA Shah, S Chen, ZH Zheng… - Nano Energy, 2022 - Elsevier
Hybrid lead-halide perovskite materials have attracted enormous attention due to their
remarkable optoelectronics properties. Within just a few years of research efforts, lead-based …

Tuning the light emission properties by band gap engineering in hybrid lead halide perovskite

V D'Innocenzo, AR Srimath Kandada… - Journal of the …, 2014 - ACS Publications
band gap of the material along with its photoluminescence lifetime. We demonstrate that larger
crystallites present smaller band gap … , organometal halide perovskites are also emerging …

Heterovalent B-site co-alloying approach for halide perovskite bandgap engineering

K Du, X Wang, Q Han, Y Yan, DB Mitzi - ACS Energy Letters, 2017 - ACS Publications
… for compositional engineering on the B site of halide perovskites—eg, … , we find that the
bandgap reduction is attributed to a … engineering flexibility within the halide perovskite family. …

Invalidity of Band-Gap Engineering Concept for Bi3+ Heterovalent Doping in CsPbBr3 Halide Perovskite

OA Lozhkina, AA Murashkina… - The journal of …, 2018 - ACS Publications
… defects, and it is not assosiated with band-gap narrowing. Bismuth doping leads to a broadening
… of the band-gap engineering in Bi 3+ -doped CsPbBr 3 halide perovskite is not valid. …

Bandgap Engineering of Lead-Halide Perovskite-Type Ferroelectrics.

HY Ye, WQ Liao, CL Hu, Y Zhang, YM You… - … (Deerfield Beach, Fla …, 2016 - europepmc.org
Semiconducting ferroelectricity is realized in hybrid perovskite-type compounds (cyclohexylammonium)
2 PbBr4-4 x I4 x (x= 0-1). By adjusting the composition x, the bandgap is …

Bandgap engineering in two-dimensional halide perovskite Cs 3 Sb 2 I 9 nanocrystals under pressure

T Geng, Z Ma, Y Chen, Y Cao, P Lv, N Li, G Xiao - Nanoscale, 2020 - pubs.rsc.org
Halide perovskites have attracted great attention owing to their outstanding performance in
… application is impeded by the large bandgap. In this study, the bandgap of 2D Cs 3 Sb 2 I 9 …

A review on energy bandgap engineering for perovskite photovoltaics

Z Hu, Z Lin, J Su, J Zhang, J Chang, Y Hao - Solar Rrl, 2019 - Wiley Online Library
… Metal halide perovskites are … bandgap engineering strategies including impurity and pressure
as well as intermediate band (IB) and external electric field (EEF) strategies for perovskite

Band gap engineering and optoelectronic properties of all-inorganic Ruddlesden-Popper halide perovskites Cs2B (X1-uYu) 4 (B= Pb, Sn; X/Y= Cl, Br, I)

IU Haq, G Rehman, I Khan - Materials Science in Semiconductor …, 2023 - Elsevier
In this article two-dimensional Ruddlesden-Popper (2DRP) halide perovskites Cs 2 B(X 1-u
Y u ) 4 where B = Pb, Sn; X/Y = Cl, Br, I; and u = 0, 0.25, 0.5, 0.75, 1 are investigated for …