… which form a heterocyclic core formally replacing a C–H bond by a C–N bond. Although
several accounts on the use of transition metals in heterocyclic synthesis have been published, …

… the synthesis of N-heterocycles via C–N/C–C bond formation … As a consequence, in the area
of organic synthesis, the … in the green formation of N-heterocycles from amidines via metal, …

… bond forming precursors. The resulting N,S-acetals were used as convenient substrates for
the elaboration of I-substituted THBC derivatives by CC bond formation via tosyliminium ions. …

… cleavage of the NN bond of diaziridinimine by CuCl, … CN bond formation and regeneration
of CuCl catalyst. Brasche and Buchwald reported [32] a new Cu(OAc)2catalyzed synthesis of …

… 4 In contrast, the Pd-catalyzed coupling of Ar-X with alcohols still remains an elusive goal
despite its potential application in organic synthesis. Aryl ethers, including oxygen heterocycles…

… that these heterocycles can incorporate, their stereoselective preparation has become a
continuous challenge for organic synthesis practitioners. 6e10 They can be synthesized by …

… many heterocyclic systems. This first comprehensive review provides an overview of the
synthetic … importance of this synthetic principle for individual heterocycles with different ring size. …

… construction of these heterocycles involve the use of CN bond-forming reactions such …
synthesis of saturated five-membered nitrogen heterocycles via Pd-catalyzed C–N bond forming …

… new synthetic approaches to carbocyclic and N-heterocyclic four-, … The reactions involve
metalinduced bond formation patterns of … with heterocyclic ligands allows free heterocycles to be …

… possible in a total synthesis. There is much … bond forming processes through the synthesis
of these two families of natural products, which hold considerable potential for heterocyclic …