… of pendant amines incorporated into diphosphane ligands. These pendant amines function
… The hydride acceptor ability of metal cations, along with the basicity of pendant amines, are …

… is an efficient electrocatalyst for hydrogen production at the … pendant amine matching that
of the acid used for proton delivery. Additionally, the fast catalytic rates for hydrogen production …

A Ni-based electrocatalyst for H 2 production, [Ni(8P Ph 2 N C 6 H 4 Br ) 2 ](BF 4 ) 2 ,
featuring eight-membered cyclic diphosphine ligands incorporating a single amine base, 1-para-…

… that more flexible pendant amines would facilitate the … N distances and more flexible
pendant amines may assist in … other related catalysts with pendant amines that may be more …

… been studied for electrocatalytic hydrogen production using 1:1 [(… , and that the pendant
amines of these complexes facilitate … of the protonated pendant amine from the nonproductive …

… 2 oxidation and production. We find that the presence of pendant amine functional groups
greatly facilitates the heterolytic H 2 bond cleavage, resulting in a protonated amine and a Ni …

… production/oxidation of hydrogen. In this work we describe intramolecular proton transfer
between Ni and positioned pendant amines for the hydrogen … , with pendant amines positioned …

… The pendant amines used in our research are designed to function as proton relays that
deliver protons to the correct location; they facilitate both intramolecular and intermolecular …

… hydrogen addition has the protons on the pendant amines in an endo position facing the metal.
In this position, the protons are stabilized by a Ni···H–N hydrogen … –N hydrogen bond and …

… −1 is the fastest reported for a molecular hydrogen oxidation … species and a protonated
pendant amine. The transition state … Ni(0) species with two protonated pendant amines with a free …