Mononuclear dysprosium (III) complexes with triphenylphosphine oxide ligands: Controlling the coordination environment and magnetic anisotropy

SK Langley, KR Vignesh, K Holton, S Benjamin, GB Hix… - Inorganics, 2018 - mdpi.com
… A small number of other phosphine oxide based lanthanide complexes with large anisotropy
barriers have also been reported [13,14,15]. We believe bulky phosphine oxide ligands …

Tuning Magnetic Anisotropy in Co (II) Tetrahedral Carbazole-Modified Phosphine Oxide Single-Ion Magnets: Importance of Structural Distortion versus Heavy-Ion …

G Bhatt, T Sharma, SK Gupta, F Meyer… - Inorganic …, 2023 - ACS Publications
… number on the electronic, magnetic, and structural properties of high-spin cobalt(II)–halide
complexes supported by substituted phosphine oxide ligands have been investigated in the …

Phosphine Oxide Ligand Based Tetrahedral CoII Complexes with Field‐induced Slow Magnetic Relaxation Behavior Modified by Terminal Ligands

RC Yang, DR Wang, JL Liu, YF Wang… - Chemistry–An Asian …, 2019 - Wiley Online Library
… 1c Recent researches indicate that, high magnetic anisotropy … The most common source of
the magnetic anisotropy of SIMs … , which represent easy-axial anisotropy, in order to observe …

Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy (III) complex

P Kalita, N Ahmed, S Moorthy, V Béreau, AK Bar… - Dalton …, 2023 - pubs.rsc.org
… First, we recalculated the magnetic anisotropy of the previously reported [L eq DyCl 2 ] −
complex (2-Dy) using our computational methodology. Our calculations yield a highly axial g-…

Multifunctional Ln III complexes with SMM, luminescence and MCE properties constructed using selected phosphine oxide and diketonate

H Yan, ZW Che, WB Sun - New Journal of Chemistry, 2023 - pubs.rsc.org
… role in determining the magnetic anisotropy of an individual spin … , β-diketone and phosphine
oxide compounds and their … -based optical, electric, magnetic and fluorescent materials. …

… electronic structure and flexibility of the counteranions on magnetization relaxation in [Dy (L) 2 (H 2 O) 5] 3+(L= phosphine oxide derivative) pentagonal bipyramidal …

IF Díaz-Ortega, JM Herrera, S Dey, H Nojiri… - Inorganic Chemistry …, 2020 - pubs.rsc.org
… , essentially depends on the magnetic anisotropy. In this … strong single-ion magnetic anisotropy
and large unquenched … in the field, because their magnetic anisotropy can be deliberately …

Synthesis, structure, and magnetism of mono-and binuclear manganese (II) compounds of nitronyl nitroxide substituted phosphine oxides

C Rancurel, DB Leznoff, JP Sutter, S Golhen… - Inorganic …, 1999 - ACS Publications
phosphine oxide ligands are reported. The compounds [(o-nitronyl nitroxide-phenyl)diphenylphosphine
oxide]… nitroxide-phenyl) diphenylphosphine oxide]bis(hexafluoroacetylacetonato)…

Field-induced single molecule magnets of phosphine-and arsine-oxides

M Fondo, J Corredoira-Vázquez… - Frontiers in …, 2018 - frontiersin.org
magnetic anisotropy of the complex and, therefore, they suggest that one can match an
appropriate ligand field to maximize magnetic anisotropy … angle of the phosphine oxides but also …

Nuclear magnetic resonance studies. IV. Carbon and phosphorus nuclear magnetic resonance of phosphine oxides and related compounds

TA Albright, WJ Freeman… - The Journal of Organic …, 1975 - ACS Publications
… of 16 phosphine oxides and sulfides are examined. Changes in the 13C and 31P NMR of
triphenylphosphine oxide, sulfide, … The anisotropy of the sulfoxidegroup has been studied by …

Pentagonal bipyramidal Ln (III) complexes containing an axial phosphine oxide ligand: Field-induced single-ion magnetism behavior of the Dy (III) analogues

P Kalita, N Ahmed, AK Bar, S Dey, A Jana… - Inorganic …, 2020 - ACS Publications
magnetic anisotropy. With this clue a large number of monometallic Ln(III) complexes were
prepared with interesting magnetic … We thoroughly studied the magnetic properties of the Dy(III…