Intermolecular enolate heterocoupling: scope, mechanism, and application

MP DeMartino, K Chen, PS Baran - Journal of the American …, 2008 - ACS Publications
… methods for symmetrical succinate synthesis. As previously … greatly hindered in complex
molecule synthesis. Several solutions … of one carbonyl with another molecule of itself would be …

Palladium-Catalyzed C–H Amination of C(sp2) and C(sp3)–H Bonds: Mechanism and Scope for N-Based Molecule Synthesis

YN Timsina, BF Gupton, KC Ellis - ACS Catalysis, 2018 - ACS Publications
… catalysts that are useful in the field of organic synthesis. It will also briefly cover allylic
aminations … We will cover reaction development as well as mechanisms and substrate scope for …

Nickel‐Catalyzed C H Arylation of Azoles with Haloarenes: Scope, Mechanism, and Applications to the Synthesis of Bioactive Molecules

T Yamamoto, K Muto, M Komiyama… - … A European Journal, 2011 - Wiley Online Library
Novel nickel‐based catalytic systems for the CH arylation of azoles with haloarenes and aryl
triflates have been developed. We have established that Ni(OAc) 2 /bipy/LiOtBu serves as …

Transition metal catalyzed synthesis of arylamines and aryl ethers from aryl halides and triflates: Scope and mechanism

JF Hartwig - Angewandte Chemie International Edition, 1998 - Wiley Online Library
… This review covers the development of synthetic methods to form arylamines by this … the
total synthesis of biologically active molecules and two applications to the synthesis of materials …

Scope and mechanism of stannylalumination of 1-alkynes

S Sharma, AC Oehlschlager - The Journal of Organic Chemistry, 1989 - ACS Publications
… The types of organometallics used in organic synthesis have expanded in the past decade,
… Vinyl organometallics based on these metals are the synthons of choice for synthesis of regio…

[HTML][HTML] Cross-Coupling Synthesis of Methylallyl Alkenes: Scope Extension and Mechanistic Study

C Tabélé, C Curti, Y Kabri, N Primas, P Vanelle - Molecules, 2015 - mdpi.com
… This water could come from methallyl alcohol via a dehydrative pallado-catalyzed mechanism
[15], but we hypothesized instead that it comes from the dehydration of three equivalents …

Native chemical ligation and extended methods: mechanisms, catalysis, scope, and limitations

V Agouridas, O El Mahdi, V Diemer, M Cargoet… - Chemical …, 2019 - ACS Publications
synthesis of peptides and proteins, the NCL reaction has largely transcended its initial scope
… must be included in complex molecules. The use of these approaches in protein chemical …

Organolanthanide-catalyzed synthesis of phosphine-terminated polyethylenes. Scope and mechanism

AM Kawaoka, TJ Marks - Journal of the American Chemical …, 2005 - ACS Publications
… A single 31 P NMR −CH 2 P(O)Et 2 resonance at δ = 52 ppm and narrow monomodal
polydispersity suggest a single-site mechanism. The molecular weight of the polymer produced by …

Synthesis of 6-and 7-membered cyclic enaminones: Scope and mechanism

MJ Niphakis, BJ Turunen, GI Georg - The Journal of organic …, 2010 - ACS Publications
… into the scope and mechanism of this … synthetic equivalent could direct this cyclization into
well-explored mechanistic territory, providing a surer means to our desired target molecules

[HTML][HTML] The hydroarylation reaction—scope and limitations

JC Namyslo, J Storsberg, J Klinge, C Gärtner, ML Yao… - Molecules, 2010 - mdpi.com
… The mechanism of this reductive Heck reaction becomes more … to synthesize complex
structures from easily available precursors has attracted much interest in contemporary synthetic