Ligand-ligand interactions in metal complexes. Thermodynamic and spectroscopic investigation of simple and mixed copper (II) and zinc (II) substituted-malonate …

P Amico, RP Bonomo, R Cali, V Cucinotta… - Inorganic …, 1989 - ACS Publications
ligand-ligand interaction is indicated by a more favorable enthalpy change accompanying
the complex formation of mixed … The EPR parameters of mixed copper (II) complexes show …

Co-ordination of solvent molecules to square-planar mixed-ligand nickel (II) complexes: a thermodynamic and quantum-mechanical study

W Linert, A Taha - Journal of the Chemical Society, Dalton …, 1994 - pubs.rsc.org
… and isokinetic relationships 19920 to mixed-ligand … trans isomers for interaction with weaker
donor solvents. This can … , namely that strong donating solvents react via the formation of a …

Solvent extraction of metal ions with mixed ligands—I: Adduct formation of Cu (II) and Zn (II) chelate complexes of thenoyltrifluoroacetone and β-isopropyltropolone

T Sekine, D Dyrssen - Journal of Inorganic and Nuclear Chemistry, 1964 - Elsevier
… as a non-polar solvent, chloroform as a solvent with the ability to form hydrogen bonds with
the organic ligands, and methyl isobutyl ketone as a solvent in which interaction is possible …

Solvent effects in chiral ligand exchange systems

J Koska, C Mui, CA Haynes - Chemical engineering science, 2001 - Elsevier
… in mixed solvents are … solvent the electron-rich hydroxy group of the l-HyPro ligand is
pointing towards the phenyl-ring of d-Phe to establish additional electron-stacking interactions

Luminescence of mixed-ligand polypyridine-ruthenium (II) complexes in the temperature range 84-250 K. Interligand interactions and viscosity effects on radiationless …

F Barigelletti, P Belser, A Von Zelewsky… - The Journal of …, 1985 - ACS Publications
… which includes the rigid-fluid transition temperature of the solvent (4: 5 (v/v) propionitrile-…
+ complexes shows that the interaction between biq or DMCH ligands leads to measurable …

Synthesis, spectral characterization and solvent effects on the electro-reduction of mixed ligand cobalt (III) complexes

K Sivaraj, KP Elango - Journal of solution chemistry, 2010 - Springer
… specific solvent-solvent-solute interactions. The separation of solvent polarity into nonspecific
and specific solvent-solvent-… may be used to interpret solvent effects through such multiple …

Solvent effects on the stability of mixed ligand complexes

N Yellin, Y Marcus - Journal of Inorganic and Nuclear Chemistry, 1974 - Elsevier
… the solvent-solute interactions can be separated into two main parts(2-5] (a) Short-range
interactions-the interaction of the ion with the solvent … the appropriate solvent (or mixed solvent). …

Thermal, spectroscopic, and solvent influence studies on mixed-ligand copper (II) complexes containing the bulky ligand: Bis [N-(p-tolyl) imino] acenaphthene

U El-Ayaan, IM Gabr - Spectrochimica Acta Part A: Molecular and …, 2007 - Elsevier
… The observed solvatochromism is mainly due to the solute–solvent interaction between the
chelate cation and the solvent molecules. Thermal properties and decomposition kinetics of …

Ligand‐Exchange Processes on Solvated Lithium Cations: DMSO and Water/DMSO Mixtures

E Pasgreta, R Puchta, M Galle… - …, 2007 - Wiley Online Library
mixed solvents over using their pure counterparts in lithium batteries is to be able to manipulate
the suitable properties of these solvents … select a solvent with a weak interaction toward …

Mixed Ligand Complexes of N‐Methyl‐N‐phenyl Dithiocarbamate: Synthesis, Characterisation, Antifungal Activity, and Solvent Extraction Studies of the Ligand

AC Ekennia, DC Onwudiwe, C Ume… - Bioinorganic chemistry …, 2015 - Wiley Online Library
A series of mixed ligand dithiocarbamate complexes with a general formula [ML 2 (py) 2 ], …
ligand towards copper and nickel ions in different solvent media were investigated. The ligand