Controlling molecular crystal polymorphism with self-assembled monolayer templates

R Hiremath, JA Basile, SW Varney… - Journal of the American …, 2005 - ACS Publications
… Computational screening for epitaxial relationships between all MNPU faces and the cited
4‘… We note that epitaxy calculations do not distinguish between the same family of crystal faces

Calcite shape modulation through the lattice mismatch between the self-assembled monolayer template and the nucleated crystal face

B Pokroy, J Aizenberg - CrystEngComm, 2007 - pubs.rsc.org
… that the monolayer at the crystal interface is composed of small lattice-matching, defect-free
domains of tilted molecules, between which missing rows of ions are added in the crystal to …

Charge, stereochemistry, or epitaxy? Toward controlled biomimetic nucleation at mixed monolayer templates

B Stripe, A Uysal, B Lin, M Meron, P Dutta - Langmuir, 2012 - ACS Publications
face is seen under a floating monolayer template for the first time. Our results indicate that the
average template … both the organic monolayer template and growing crystals using grazing …

Organic template-directed inorganic crystallization: oriented nucleation of barium sulfate under compressed Langmuir monolayers

BR Heywood, S Mann - Journal of the American Chemical Society, 1992 - ACS Publications
… can be influenced by subsequent growth processes under the sulfate monolayers. An … of
developing crystal faces with the monolayer headgroups. Compressed carboxylate monolayers

Simulation of organic monolayers as templates for the nucleation of calcite crystals

DM Duffy, JH Harding - Langmuir, 2004 - ACS Publications
face (and hence the orientation of crystal growth) of calcite crystals on the monolayer from
… for the crystal/water interfacial energies and the crystal/monolayer interfacial energies for a …

Nucleation and growth of metastable polymorphs on siloxane monolayer templates

C Capacci-Daniel, KJ Gaskell, JA Swift - Crystal growth & design, 2010 - ACS Publications
… SAMs as crystallization templates for molecular crystals using MNPU … stabilization asserted
for Au−S monolayer templates. … the contacting growth face by single crystal XRD goniometry, …

Template-directed inorganic crystallization: oriented nucleation of barium sulfate under Langmuir monolayers of an aliphatic long chain phosphonate

BR Heywood, S Mann - Langmuir, 1992 - ACS Publications
Crystals grown in the absence of a monolayer were collected on glass coverslips placed …
The structural homology established between the monolayer and the (100) face of the incipient …

Crystal growth on self-assembled monolayers

A Singh, IS Lee, K Kim, AS Myerson - CrystEngComm, 2011 - pubs.rsc.org
monolayers attractive templates for nucleation and crystal … of the monolayer surface, and the
crystal face. Inspection of … formed between the monolayer surface and crystal face. Similarly …

Highly oriented self-assembled monolayers as templates for epitaxial calcite growth

AM Travaille, L Kaptijn, P Verwer… - Journal of the …, 2003 - ACS Publications
monolayer is homogeneous all over the substrate and if a unique interaction exists between
the monolayer and the calcite face … a method to laterally align calcite crystals using a SAM of …

[PDF][PDF] Face-selective nucleation of calcite on self-assembled monolayers of alkanethiols: effect of the parity of the alkyl chain

YJ Han, J Aizenberg - … Chemie International Edition, 2003 - aizenberglab.seas.harvard.edu
face-selective nucleation of calcite cannot be explained in terms of the lattice match between
the SAM and the crystal face it … of a biological macromolecular template would result in the …