Polymer/nanoparticle interactions: bridging the gap

YN Pandey, GJ Papakonstantopoulos… - …, 2013 - ACS Publications
Nanoparticles were well-dispersed for values of R = N/P > 0.24, suggesting that aggregation
required much longer free polymer chains… different polymer chemical architectures, surfaces

Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
… hydroxyls on the surface of SiO 2 NPs leads to a strong NP-polymer interaction (estimated …
far from the NP surface (α 1 ) and slower relaxations near the NP-polymer interface (α 2 ). The …

Polymers on nanoparticles: structure & dynamics

MJA Hore - Soft Matter, 2019 - pubs.rsc.org
… Starting from the case of a single polymer chain attached to a nanoparticle core, this Review
… in characterizing the structure of polymers on nanoparticle surface and their corresponding …

Polymer chain dynamics and glass transition in athermal polymer/nanoparticle mixtures

H Oh, PF Green - Nature materials, 2009 - nature.com
… spends most of its time in the host environment, and not at the nanoparticle surface, the
temperature dependence of the relaxations should not be affected appreciably. Note that if the …

Distribution in the grafting density of end-functionalized polymer chains adsorbed onto nanoparticle surfaces

FT Oyerokun, RA Vaia - Macromolecules, 2012 - ACS Publications
… for the fraction of nanoparticles with n polymer chains attached to their curved … ” nanoparticles
(ie, nanoparticles with no polymer chains attached) and singly dispersed polymer chains, …

Surface initiated polymerization from nanoparticle surfaces

RC Advincula - Journal of Dispersion Science and Technology, 2003 - Taylor & Francis
nanoparticle surfaces by the use of polymers. The purpose is to directly tether polymers from
or onto the surface of these nanoparticlesPolymer brushes are polymer chains tethered by …

A molecular dynamics simulation study of nanoparticle interactions in a model polymer-nanoparticle composite

JS Smith, D Bedrov, GD Smith - Composites science and technology, 2003 - Elsevier
… Increasingly attractive nanoparticlepolymer interactions led to strong adsorption of the
polymer chains on the surface of the nanoparticles and promoted dispersion of the nanoparticles

Relaxation dynamics of nanoparticle-tethered polymer chains

SA Kim, R Mangal, LA Archer - Macromolecules, 2015 - ACS Publications
… of polymer chains tethered to a nanoparticle surface … influence on overall polymer dynamics
as those originating from chain … (PI) chains, we find that tethering to the nanoparticle surface

Roles of polymer ligands in nanoparticle stabilization

RB Grubbs - Polymer Reviews, 2007 - Taylor & Francis
… The methods for integration of nanoparticles with polymerpolymer chains are directly
associated with the nanoparticle … living polymerization initiating species to nanoparticle surfaces

Polymernanoparticle interfacial behavior revisited: A molecular dynamics study

J Liu, Y Wu, J Shen, Y Gao, L Zhang… - Physical Chemistry …, 2011 - pubs.rsc.org
… 3.1 Polymer chains and single nanoparticle … state of polymer chains on the filler surface,
firstly we simulate the case with one polymer chain and one nanoparticle, by changing the …