… for both H 2 oxidation and production. We find that the presence of pendant amine functional
groups greatly facilitates the heterolytic H 2 bond cleavage, resulting in a protonated amine …

… of pendant amines incorporated into diphosphane ligands. These pendant amines function
… The hydride acceptor ability of metal cations, along with the basicity of pendant amines, are …

… (basicity of the amine) and the relative positioning of the pendant amine to the metal, a …
other diphosphines bearing pendant amines, and key structural features of pendant amines are …

… oxidation of hydrogen. In this work we describe intramolecular proton transfer between Ni
and positioned pendant amines for the hydrogen oxidation electrocatalyst [Ni(P Cy 2 N Bn 2 H) …

… that more flexible pendant amines would facilitate the … N distances and more flexible
pendant amines may assist in … other related catalysts with pendant amines that may be more …

… heretofore for any other synthetic molecular H 2 oxidation … The H 2 adduct then undergoes
heterolytic H 2 cleavage resulting in a Ni 2+ hydride species and a protonated pendant amine. …

… In the first step, H 2 binds to iron to form a dihydrogen complex, and many examples of …
molecule is heterolytically cleaved to form an iron hydride and a protonated pendant amine [Fe(H)…

… (5-CF 3 , 5-Cl and 5-Br) are below that of [(DMF)H] + , resulting in slow (… pendant amine
substituents have a greater electron-donating ability than the H atom in 5-H, the pendant amine is …

… H 2 production catalyst [Ni(8P Ph 2 N C 6 H 4 Br ) 2 ](BF 4 ) 2 (abbreviated as [Ni(8P 2 N)
2 ] 2+ ) that contains only one pendant amine … reported [Ni(P Ph 2 N C 6 H 4 Br 2 ) 2 ] 2+ (…

… a pendant amine in the active site that is believed to be properly positioned to facilitate formation
and cleavage of the H–H … diphosphine ligand with two pendant amines, and R and R′ …