Chemoselective hydrogenation and transfer hydrogenation of aldehydes catalyzed by iron (II) PONOP pincer complexes

S Mazza, R Scopelliti, X Hu - Organometallics, 2015 - ACS Publications
… and chemoselectivity of iron catalysis warrant further improvement. Here we report new iron
pincer complexes as chemoselective hydrogenation and transfer hydrogenation catalysts. …

Room temperature chemoselective hydrogenation of CC, CO and CN bonds by using a well-defined mixed donor Mn (i) pincer catalyst

AB Shabade, DM Sharma, P Bajpai, RG Gonnade… - Chemical Science, 2022 - Elsevier
… exceptional chemoselective catalytic reduction of unsaturated bonds. This hydrogenation
protocol … The CC bond is chemoselectively hydrogenated in α,β-unsaturated ketones, while the …

Chemoselective supported ionic-liquid-phase (SILP) aldehyde hydrogenation catalyzed by an Fe (II) PNP pincer complex

J Brünig, Z Csendes, S Weber, N Gorgas… - ACS …, 2018 - ACS Publications
… novel Fe(II) PNP pincer complex-based SILP system, which was fully characterized and used
as a hydrogenation catalyst for the chemoselective hydrogenation of aromatic and aliphatic …

Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions

S Cohen, AN Bilyachenko… - European Journal of …, 2019 - Wiley Online Library
… on the chemoselective transfer hydrogenation of nitroarenes … catalyzed by a series of pincer
catalysts equipped with different … PC(sp 3 )P pincer complexes were employed in this study …

Mild and selective hydrogenation of aromatic and aliphatic (di) nitriles with a well-defined iron pincer complex

C Bornschein, S Werkmeister, B Wendt, H Jiao… - Nature …, 2014 - nature.com
complex, which allows for the hydrogenation of aryl, alkyl, heterocyclic nitriles and dinitriles.
By using an iron PNP pincer complex… Notably, our complex constitutes the first example of an …

Chemoselective hydrogenation of aldehydes under mild, base-free conditions: manganese outperforms rhenium

M Glatz, B Stöger, D Himmelbauer, LF Veiros… - ACS …, 2018 - ACS Publications
… Several hydride Mn(I) and Re(I) PNP pincer complexes were applied as catalysts for the
homogeneous chemoselective hydrogenation of aldehydes. Among these, [Mn(PNP-iPr)(CO) 2 (…

Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism

T Leischner, LA Suarez, A Spannenberg, K Junge… - Chemical …, 2019 - pubs.rsc.org
pincer complexes has been shown for the first time to be active in the catalytic hydrogenation
of … Notably, high chemoselectivity was observed in the presence of certain reducible groups …

Chemoselective Transfer Hydrogenation of Enamides Using Ru Pincer Complexes for the Synthesis of α-Amino Acids

DLJ Pinheiro, M Nielsen - The Journal of Organic Chemistry, 2022 - ACS Publications
… In summary, we have developed the first transfer hydrogenation catalyzed by Ru pincer
complexes of enamides. The efficient and chemoselective protocol permitted the conversion of …

Efficient hydrogenation of ketones and aldehydes catalyzed by well-defined iron (II) PNP pincer complexes: evidence for an insertion mechanism

N Gorgas, B Stöger, LF Veiros, E Pittenauer… - …, 2014 - ACS Publications
… Interestingly, complex [Fe(PNP Me -iPr)(H)(CO)(Br)], featuring NMe … chemoselective
hydrogenation of aldehydes. The first type of complexes involves deprotonation of the PNP ligand as …

Direct heterogenization of the Ru-Macho catalyst for the chemoselective hydrogenation of α, β-unsaturated carbonyl compounds

S Padmanaban, GH Gunasekar, S Yoon - Inorganic Chemistry, 2021 - ACS Publications
… available homogeneous pincer-type complex, Ru-Macho, … -linker to obtain a heterogeneous,
pincer-type Ru porous organometallic … catalyst for the chemoselective hydrogenation of α,β-…