… pathways that also reflect upon the polymerization of TMC. Scheme 4 illustrates and …
trimethylene carbonate. When comparing the two guanidines and the amidine base (1−3), polymers …

… trimethylene carbonate. This paves the way to the synthesis of as much as 50-fold polymer
… This is the first example of an “immortal” polymerization of a carbonate monomer. In addition…

… Another cyclic ester monomer of biomedical interest is trimethylene carbonate, TMC, a cyclic
carbonate ester that can be ring-opened to yield poly(trimethylene carbonate), PTMC, first …

The controlled “immortal” ring‐opening polymerization of trimethylene carbonate (TMC) using
a two‐component catalyst system based on a metal Lewis acid, such as a metal triflate M(…

… use of lipase-catalyzed ring-opening polymerizations to cyclic carbonate monomers. Of the
seven lipases screened for bulk trimethylene carbonate (TMC) polymerization (70 C, 120 h), …

… via ring-opening polymerization of trimethylene carbonate using 1,8-diazabicyclo[5.4.0]undec-7-ene
and thiourea as organocatalysts. Following polymer isolation, students cool the …

… The polymer poly(trimethylene carbonate)-… trimethylene carbonate (TMC) and δ-valerolactone
(δ-VL) was carried out to achieve the diblock copolymerization of trimethylene carbonate (…

… The ring-opening polymerization (ROP) of trimethylene carbonate (TMC) catalyzed by … The
polymerization conditions were optimized to afford well-defined polytrimethylene carbonates (…

… In conclusion, the synthesis of poly(trimethylene carbonate) is reported through … polymerization
most likely proceeds by formation of trimethylene carbonate monomer that is polymerized …

Aluminum and tin salen complexes have been shown to effectively catalyze the ring-opening
polymerization (ROP) of trimethylene carbonate (TMC) to polycarbonate. The most active …