Reciprocal regulation between MOFs and polymers

A Nishijima, Y Kametani, T Uemura - Coordination Chemistry Reviews, 2022 - Elsevier
… the reciprocal relationship between MOFs and polymers that … regulation of polymers by
MOFs (“MOFs for polymers”), where characteristics of MOF pores influence the controlled polymer

In situ coordinated ultrathin MOF-polymer electrolyte membrane with vertically aligned transfer channels for solid lithium metal batteries

X Qi, S Zhang, Y Li, X Li, F Chu, X Wang, M Yu… - Journal of Membrane …, 2024 - Elsevier
… This work provides a novel, high efficiency and facile route to prepare MOF-polymer
composite membranes with controllable MOF distribution accurately. And then the PVDF-HFP@ZIF-…

Interfacial polymerization of MOF “monomers” to fabricate flexible and thin membranes for molecular separation with ultrafast water transport

X Cui, G Kong, Y Feng, L Li, W Fan, J Pang… - Journal of Materials …, 2021 - pubs.rsc.org
… In this work (Scheme 1 right), ultra-small MOF particles directly served as a kind of “ordered
porous monomer” to carry out interfacial polymerization with common organic monomers to …

Fabrication of Polyelectrolyte Sheets of Unimolecular Thickness via MOF-Templated Polymerization

A Nishijima, Y Hayashi, K Mayumi, N Hosono… - …, 2023 - ACS Publications
… place in a 2D-regulated manner, rendering the resulting network polymers into 2D sheets
of … by exploiting this MOF-templated method (Figure 1). The polymerization of methyl …

Polymer networks: from plastics and gels to porous frameworks

Y Gu, J Zhao, JA Johnson - Angewandte Chemie International …, 2020 - Wiley Online Library
… The reciprocal of the critical frequency ω c where G′(ω)=G′′(ω), which is referred to as
the … discuss two major types of crystalline microporous polymer networks: MOFs and COFs. …

Synergic catalysts of polyoxometalate@ cationic porous aromatic frameworks: reciprocal modulation of both capture and conversion materials

J Song, Y Li, P Cao, X Jing, M Faheem… - Advanced …, 2019 - Wiley Online Library
… As an emerging class of highly porous materials with comparable porosity of MOFs, the
porous … Conjugated microporous polymers with metal sites of Co or Al were reported with the …

Role of filler porosity and filler/polymer interface volume in metal–organic framework/polymer mixed-matrix membranes for gas separation

A Nuhnen, D Dietrich, S Millan… - ACS applied materials & …, 2018 - ACS Publications
… the reciprocal specific free fractional volume (sFFV) rules out … of the polymer and the
MOF, but not the polymer–filler … of the polymer, the MOF and the void volume of the MOFpolymer

Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina… - Angewandte Chemie …, 2023 - Wiley Online Library
polymerization of a divinyl monomer. However, the polymerization of p-DVB in an isostructural
copper MOF … , was not successful, and no trace of the polymeric product was observed. …

Bimetallic-MOF Tunable Conductive Hydrogels to Unleash High Stretchability and Sensitivity for Highly Responsive Flexible Sensors and Artificial Skin Applications

M Khan, LA Shah, Hifsa., HM Yoo… - ACS Applied Polymer …, 2024 - ACS Publications
polymer composites, an alternative method involves integrating MOF particles into polymer
substrates through blending, offering robust and flexible MOFpolymer composites. This …

[PDF][PDF] Synthesis, Encapsulation, and Templating of Polymers Mediated by Metal-organic Frameworks

T Uemura - synchrotron-soleil.fr
… of nanocomposites between MOFs and polymers will provide … radical polymerization of vinyl
monomers can be attained in MOFpolymers. 2 For example, stereo-and regioregularity of …