Visible light-promoted dearomative [2+ 2] cycloaddition of indole derivatives tethered with
olefins at the N1 position has been considered thermodynamically unfeasible due to the …

Regiodivergent asymmetric cycloadditions from the same set of starting materials offer
interesting opportunities for rapid construction of optically active cyclic molecules with …

Thanks to the impressive control that microenvironments within enzymes can have over
substrates, many biological reactions occur with high regio-and stereoselectivity. However …

Enzymes facilitate chemical conversions through the collective activity of aggregated
components, but the marriage of aggregation‐induced emission (AIE) with molecular …

Photochemical electrocyclization reactions are valued for both their ability to produce
structurally complex molecules and their central role in elucidating fundamental mechanistic …

A first-row transition metal complex, Cu (dmp)(DPEPhos) BF4, promotes the synthesis of
boracyclobutanes (11 examples, 38→ 87%) and 2-oxa-BCHs (10 examples, 55→ 90%) via …

Here, we present an in-depth analysis of structural factors that modulate peptide-capped
nanoparticle catalytic activity via optically driven structural reconfiguration of the biointerface …

The efficient generation of high structural complexity, which correlates with the number of
stereocentres, is an important objective in organic synthesis. Ideally, from a perspective of …

Cage catalysis continues to create significant interest, yet catalyst function remains poorly
understood. Herein, we report mechanistic insights into coordination-cage-catalyzed …

Although highly appealing for rapid access of molecular complexity, multi‐functionalization
of alkenes that allows incorporation of more than two functional groups remains a prominent …