Supramolecular and covalent polymers share multiple structural effects such as chiral
amplification, helical inversion, sergeants and soldiers, or majority rules, among others …

Supramolecular and covalent polymers share multiple structural effects such as
communication mechanisms among monomer repeating units, which are related to their …

The synthetic pursuit of π-conjugated (and cross-conjugated) macromolecules possessing
well-defined architectures is driven by the desire to impart specific physical properties onto …

We review recent progress in hierarchically self-assembled helical aromatic π-conjugated
polymers (ACPs) by focusing on (i) the intrachain helicity of ACPs in which the main chain …

New helical poly (phenylacetylene) s have been successfully designed and synthesised and
their properties checked. The new polymers behave as sensors of metal cation valences …

Biological macromolecules, such as DNA and proteins, possess a unique and specific
ordered structure, such as a right-handed double helix or a single α-helix. Those structures …

Controlling the one-handed helicity in synthetic polymers is crucial for developing helical
polymer-based advanced chiral materials. We now report that an extremely small amount of …

Preparation of helical structures à la carte by monomer design of dynamic helical polymers
such as poly (phenylacetylene) s (PPAs) is a difficult task due to conformational freedom of …

Both the role of the absolute configuration and the tendency of a chiral monomer to promote
a certain helical scaffold in a poly (phenylacetylene)(PPA) have been evaluated to study the …

A novel class of stereocomplexes is described by the interaction of helically complementary
poly (phenylacetylene) s (PPAs) carrying an α-methoxy-α-trifluoromethylphenylacetamide …