Radical mediated thiol-yne polymerization reactions complement the more well-known thiol-
ene radical polymerization processes, with the added advantage of increased functionality …

Radical mediated addition-fragmentation chain transfer of mid-chain allyl sulfide functional
groups was utilized to reduce polymerization-induced shrinkage stress in thiol-yne step …

The in situ generation of thiols by nucleophilic ring-opening of a thiolactone with amines,
followed by a UV-initiated radical thiol− ene reaction in a one-pot fashion, has been …

A new use of the thiol‐ene reaction to generate functional, redox‐tunable polymers is
described. To illustrate the versatility of this approach, tailored divinyl ether monomers were …

The developments in synthetic polymer chemistry have devoted to meet the huge demand
required to create efficient, high yield, and operationally simple chemical methods that can …

As a tribute to Professor Charlie Hoyle, we take the opportunity to review the impact of thiol‐
ene chemistry on polymer and materials science over the past 5 years. During this time, a …

Multifunctional alkynes (2, 3, or 4 ynes per monomer) were prepared utilizing the
nucleophile-catalyzed thio− Michael addition reaction from commercially available …

Recent years have witnessed an increase in the utilization of stimuli-responsive polymers in
various areas of materials and biological sciences. In particular, disulfide linkage containing …

The thiol–epoxy 'click'process is employed as a polymerization reaction to prepare linear
polymer chains substituted with free hydroxyl groups. Post-polymerization modification of the …

Thiol− isocyanate− ene ternary networks with systematic variations (100/100/0, 100/80/20,
100/60/40, 100/40/60, 100/20/80, and 100/0/100) were prepared by sequential and …