Polymerization of trimethylene carbonates using organic phosphoric acids

J Liu, S Cui, Z Li, S Xu, J Xu, X Pan, Y Liu, H Dong… - Polymer …, 2016 - pubs.rsc.org
The homopolymerization of trimethylene carbonates (TMC) and their diblock
copolymerization to PTMC-b-PVL and PTMC-b-PCL were carried out using benzyl alcohol …

Phosphoramidic acid catalyzed controlled/living ring-opening polymerization of trimethylene carbonate

J Chen, S Kan, H Xia, F Zhou, X Chen, X Jiang, K Guo… - Polymer, 2013 - Elsevier
The ring-opening polymerization (ROP) of trimethylene carbonate (TMC) catalyzed by
phosphoramidic acid (PAA) and initiated with benzyl alcohol (BnOH) has been investigated …

Diphenyl phosphate as an efficient acidic organocatalyst for controlled/living ring-opening polymerization of trimethylene carbonates leading to block, end …

K Makiguchi, Y Ogasawara, S Kikuchi, T Satoh… - …, 2013 - ACS Publications
The ring-opening polymerization (ROP) of cyclic carbonates with diphenyl phosphate (DPP)
as the organocatalyst and 3-phenyl-1-propanol (PPA) as the initiator has been studied using …

Bifunctional imidodiphosphoric acid‐catalyzed controlled/living ring‐opening polymerization of trimethylene carbonate resulting block, α, ω‐dihydroxy telechelic, and …

X He, Y Ji, Y Jin, S Kan, H Xia, J Chen… - Journal of Polymer …, 2014 - Wiley Online Library
The ring‐opening polymerization (ROP) of trimethylene carbonate (TMC) using
imidodiphosphoric acid (IDPA) as the organocatalyst and benzyl alcohol (BnOH) as the …

Ring-Opening Polymerization of Trimethylene Carbonate with Phosphazene Organocatalyst

J Zhu, X Luo, X Li - Polymers, 2023 - mdpi.com
Aliphatic polycarbonate (APC) compounds are an important class of biodegradable
materials with excellent biocompatibility, good biodegradability, and low toxicity, and the …

Squaramide and amine binary H-bond organocatalysis in polymerizations of cyclic carbonates, lactones, and lactides

J Liu, J Xu, Z Li, S Xu, X Wang, H Wang, T Guo… - Polymer …, 2017 - pubs.rsc.org
Multiple combinations of six squaramides (Sq) and eight amines as the co-catalysts were
tried in ring-opening polymerizations (ROPs) of cyclic carbonates, lactones, and lactides. Sq …

Metal‐free ring‐opening block copolymerization of glycidyl phenyl ether with trimethylene carbonate initiated by tetra‐n‐butylammonium fluoride

H Morinaga, Y Ujihara, T Endo - Journal of Polymer Science …, 2012 - Wiley Online Library
INTRODUCTION Aliphatic polycarbonates, obtained from ring-opening polymerization of
cyclic carbonates such as trimethylene carbonate (TC) and 2, 2-dimethyltrimethylene …

Ring‐opening polymerization of six‐membered cyclic carbonates initiated by ethanol amine derivatives and their application to protonated or quaternary ammonium …

H Matsukizono, T Endo - Journal of Polymer Science Part A …, 2016 - Wiley Online Library
Ring‐opening polymerization (ROP) of monofunctional neopentylglycol carbonate (NPGC)
with or without bifunctional di (trimethylolpropane) carbonate (DTMPC), which are derived …

Synthesis and properties of polycarbonate copolymers of trimethylene carbonate and 2‐phenyl‐5, 5‐bis (hydroxymethyl) trimethylene carbonate

ZM Li, GP Yan, CW Ai, Q Zhang, L Li… - Journal of applied …, 2012 - Wiley Online Library
The polycarbonate copolymers poly [trimethylene carbonate‐co‐2‐phenyl‐5, 5‐bis
(hydroxymethyl) trimethylene carbonate][P (TMC‐co‐PTC)] were synthesized by the ring …

High Molar Mass Poly(trimethylene carbonate) by Ph2BiOEt and Ph2BiBr-Initiated Ring-Opening Polymerizations

HR Kricheldorf, G Behnken, G Schwarz… - … Science®, Part A …, 2009 - Taylor & Francis
Trimethylene carbonate,(TMC), was polymerized in bulk with Ph2BiOEt or Ph2BiBr as
initiators. The dependence of the molecular weight on the monomer-initiator ratio (M/I) and …