Metal–Organic Framework (MOF)‐based materials as heterogeneous catalysts for C− H bond activation

M Liu, J Wu, H Hou - Chemistry–A European Journal, 2019 - Wiley Online Library
Converting light hydrocarbons such as methane, ethane, propane, and cyclohexane into
value‐added chemicals and fuel products by means of direct C− H functionalization is an …

Formation of C–C and C–heteroatom bonds by C–H activation by metal organic frameworks as catalysts or supports

A Dhakshinamoorthy, AM Asiri, H Garcia - ACS Catalysis, 2018 - ACS Publications
Cross-coupling reactions catalyzed by transition metals are currently among the most widely
used transformations in organic synthesis. In most of these reactions, the coupling involves …

Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …

S Daliran, AR Oveisi, Y Peng… - Chemical Society …, 2022 - pubs.rsc.org
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry: CO, CO2 and CH4

WG Cui, GY Zhang, TL Hu, XH Bu - Coordination Chemistry Reviews, 2019 - Elsevier
Catalysis of C1 chemistry, especially for carbon monoxide (CO), carbon dioxide (CO 2) and
methane (CH 4), is critically important for the clean production of fuels and chemicals and …

Metal–organic frameworks catalyzed C–C and C–heteroatom coupling reactions

A Dhakshinamoorthy, AM Asiri, H Garcia - Chemical Society Reviews, 2015 - pubs.rsc.org
Metal organic frameworks (MOFs) are porous crystalline solids whose structure is formed by
metal ions or clusters of a few metal ions held in place by bi-or multipodal organic linkers. In …

Metal–organic frameworks with catalytic centers: From synthesis to catalytic application

YS Kang, Y Lu, K Chen, Y Zhao, P Wang… - Coordination chemistry …, 2019 - Elsevier
Abstract Metal-organic frameworks (MOFs), as a new stable class of hybrid materials
synthesized, regulated and decorated by rational incorporating organic bridging ligands and …

Site isolation in metal–organic frameworks enables novel transition metal catalysis

T Drake, P Ji, W Lin - Accounts of chemical research, 2018 - ACS Publications
Conspectus Comprising periodically repeating inorganic nodes and organic linkers, metal–
organic frameworks (MOFs) represent a novel class of porous molecular solids with well …

Inserting CO2 into Aryl C−H Bonds of Metal–Organic Frameworks: CO2 Utilization for Direct Heterogeneous C−H Activation

WY Gao, H Wu, K Leng, Y Sun, S Ma - Angewandte Chemie, 2016 - Wiley Online Library
Described for the first time is that carbon dioxide (CO2) can be successfully inserted into aryl
C− H bonds of the backbone of a metal–organic framework (MOF) to generate free …

Computational Screening of Bimetal-Functionalized Zr6O8 MOF Nodes for Methane C–H Bond Activation

DR Pahls, MA Ortuño, PH Winegar, CJ Cramer… - Inorganic …, 2017 - ACS Publications
Zr-based metal–organic frameworks (MOFs) are promising supports for copper-based
catalysts able to activate methane. Homo-and heterobimetal-functionalized NU-1000 MOF …

Toward “metalloMOFzymes”: Metal–Organic Frameworks with Single-Site Metal Catalysts for Small-Molecule Transformations

SM Cohen, Z Zhang, JA Boissonnault - Inorganic Chemistry, 2016 - ACS Publications
Metal–organic frameworks (MOFs) are being increasingly studied as scaffolds and supports
for catalysis. The solid-state structures of MOFs, combined with their high porosity, suggest …