Distribution in the grafting density of end-functionalized polymer chains adsorbed onto nanoparticle surfaces
FT Oyerokun, RA Vaia - Macromolecules, 2012 - ACS Publications
We have developed a simple model to quantify the role of curvature on the surface
composition of polymer–nanoparticle hybrids formed as a result of the adsorption of end …
composition of polymer–nanoparticle hybrids formed as a result of the adsorption of end …
Effect of bidispersity in grafted chain length on grafted chain conformations and potential of mean force between polymer grafted nanoparticles in a homopolymer …
In efforts to produce polymeric materials with tailored physical properties, significant interest
has grown around the ability to control the spatial organization of nanoparticles in polymer …
has grown around the ability to control the spatial organization of nanoparticles in polymer …
Identifying the ideal characteristics of the grafted polymer chain length distribution for maximizing dispersion of polymer grafted nanoparticles in a polymer matrix
TB Martin, A Jayaraman - Macromolecules, 2013 - ACS Publications
We investigate, using theory and simulations, the role of the short and long grafted chains in
polydisperse polymer grafted nanoparticles in stabilizing particle dispersion in a chemically …
polydisperse polymer grafted nanoparticles in stabilizing particle dispersion in a chemically …
The structure of chain end-grafted nanoparticle/homopolymer nanocomposites
PF Green - Soft Matter, 2011 - pubs.rsc.org
The morphological structure of mixtures of homopolymers with inorganic nanoparticles, onto
which polymer chain ends are grafted, is described herein. In the bulk, at very low grafting …
which polymer chain ends are grafted, is described herein. In the bulk, at very low grafting …
Polymer grafted nanoparticles: Effect of chemical and physical heterogeneity in polymer grafts on particle assembly and dispersion
A Jayaraman - Journal of Polymer Science Part B: Polymer …, 2013 - Wiley Online Library
Macroscopic properties of polymer nanocomposites depend on the microscopic composite
morphology of the constituent nanoparticles and polymer matrix. One way to control the …
morphology of the constituent nanoparticles and polymer matrix. One way to control the …
Effective interactions and self-assembly of hybrid polymer grafted nanoparticles in a homopolymer matrix
A Jayaraman, KS Schweizer - Macromolecules, 2009 - ACS Publications
We apply the microscopic polymer reference interaction site model integral equation theory
to study the structure and phase behavior of spherical nanoparticles with six symmetrically …
to study the structure and phase behavior of spherical nanoparticles with six symmetrically …
Polymers on nanoparticles: structure & dynamics
MJA Hore - Soft Matter, 2019 - pubs.rsc.org
Grafting polymers to nanoparticle surfaces influences properties from the conformation of the
polymer chains to the dispersion and assembly of nanoparticles within a polymeric material …
polymer chains to the dispersion and assembly of nanoparticles within a polymeric material …
Scaling laws for polymer chains grafted onto nanoparticles
An experimental approach is presented for identifying the scaling laws for polymer chains
grafted onto gold nanoparticles. Poly (ethylene oxide) of various molecular weights are …
grafted onto gold nanoparticles. Poly (ethylene oxide) of various molecular weights are …
Polymer-grafted-nanoparticle surfactants
D Maillard, SK Kumar, A Rungta, BC Benicewicz… - Nano …, 2011 - ACS Publications
We have studied the surface behavior of nanoparticles, which are lightly grafted with
polymer chains, when they are mixed with matrix chains of the same architecture as the …
polymer chains, when they are mixed with matrix chains of the same architecture as the …
Structure–property relationships of polymer-grafted nanospheres for designing advanced nanocomposites
Polymer-grafted nanoparticles are an important component of many classes of polymer
nanocomposites. Here, we review the structure of polymer brushes on spherical …
nanocomposites. Here, we review the structure of polymer brushes on spherical …