Magneto-structural correlations in arsenic-and selenium-ligated dysprosium single-molecule magnets

T Pugh, V Vieru, LF Chibotaru, RA Layfield - Chemical Science, 2016 - pubs.rsc.org
The structures and magnetic properties of the arsenic-and selenium-ligated dysprosium
single-molecule magnets (SMMs)[Cp′ 3Dy (AsH2Mes)](3-Dy),[(η5-Cp′ 2Dy){μ-As (H) …

Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes

LR Thomas-Hargreaves, MJ Giansiracusa… - Chemical …, 2021 - pubs.rsc.org
Treatment of the new methanediide–methanide complex [Dy (SCS)(SCSH)(THF)](1Dy,
SCS={C (PPh2S) 2} 2−) with alkali metal alkyls and auxillary ethers produces the bis …

Cis–trans isomerism modulates the magnetic relaxation of dysprosium single-molecule magnets

J Wu, J Jung, P Zhang, H Zhang, J Tang… - Chemical …, 2016 - pubs.rsc.org
Geometry and magnetic relaxation modulations in a series of mononuclear dysprosium
complexes,[DyLz2 (o-vanilin) 2]· X· solvent (Lz= 6-pyridin-2-yl-[1, 3, 5] triazine-2, 4-diamine; …

A Study of Magnetic Relaxation in Dysprosium (III) Single‐Molecule Magnets

YS Ding, T Han, YQ Zhai, D Reta… - … A European Journal, 2020 - Wiley Online Library
Although the development of single‐molecule magnets (SMMs) is rapid, there are only two
families of high energy barrier (Ueff) dysprosium (III) SMMs known so far: the …

Relaxation dynamics of dysprosium (III) single molecule magnets

YN Guo, GF Xu, Y Guo, J Tang - Dalton Transactions, 2011 - pubs.rsc.org
Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …

Isolation of a bent dysprosium bis (amide) single-molecule magnet

J Emerson-King, GK Gransbury… - Journal of the …, 2024 - ACS Publications
The isolation of formally two-coordinate lanthanide (Ln) complexes is synthetically
challenging, due to predominantly ionic Ln bonding regimes favoring high coordination …

Tuning the Magnetic Interactions and Relaxation Dynamics of Dy2 Single‐Molecule Magnets

S Xue, YN Guo, L Ungur, J Tang… - … –A European Journal, 2015 - Wiley Online Library
Efficient modulation of single‐molecule magnet (SMM) behavior was realized by deliberate
structural modification of the Dy2 cores of [Dy2 (a′ povh) 2 (OAc) 2 (DMF) 2](1) and …

Significant enhancement of energy barriers in dinuclear dysprosium single-molecule magnets through electron-withdrawing effects

F Habib, G Brunet, V Vieru, I Korobkov… - Journal of the …, 2013 - ACS Publications
The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule
Magnets (SMMs) is investigated. By introducing highly electron-withdrawing atoms on …

Electrostatic potential determined magnetic dynamics observed in two mononuclear β-diketone dysprosium (III) single-molecule magnets

PP Cen, S Zhang, XY Liu, WM Song… - Inorganic …, 2017 - ACS Publications
Two β-diketone mononuclear Dy (III) compounds, formulated as Dy (BTFA) 3 (H2O) 2 (1)
and Dy (BTFA) 3 (bpy)(2)(BTFA= 3-benzoyl-1, 1, 1-trifluoroacetone, bpy= 2, 2′-bipyridine) …

Dramatic impact of the lattice solvent on the dynamic magnetic relaxation of dinuclear dysprosium single-molecule magnets

WY Zhang, YQ Zhang, SD Jiang, WB Sun… - Inorganic Chemistry …, 2018 - pubs.rsc.org
Two dinuclear dysprosium single-molecule magnets (SMMs) with a nearly identical core
structure, namely [Dy2 (DMOP) 2 (DBM) 4 (CHCl3) 4](1) and [Dy2 (DMOP) 2 (DBM) 4 …