Recently, the choice of ligand and geometric control of mononuclear complexes, which can
affect the relaxation pathways and blocking temperature, have received wide attention in the …

A series of mononuclear seven-coordinate Co (II) complexes [CoII (BPA-TPA)](ClO4) 2· H2O
(2-ClO4),[CoII (BPA-TPA)](PF6) 2 (3-PF6) and [CoII (BPA-TPA)](BPh4) 2 (4-BPh4) have …

In this work we report two pentacoordinated CoII–P4X1 Single Ion Magnets (SIMs) based on
P-donor ligands. The tetradentate ligand tris [2-(diphenylphosphino) ethyl] phosphine allows …

A series of tetrahedral CoII complexes [CoLX2](X= NCS (1), Cl (2), Br (3) and I (4); L= 9, 9-
dimethyl-4, 5-bis (diphenylphosphino) xanthene) based on a P-donor ligand has been …

Magnetic anisotropy is the key element in the construction of single‐ion magnets, a kind of
nanomagnets for high‐density information storage. This works describes an unusual large …

Three mononuclear Co (II) complexes with the formulas of [Co (L1) 2](1),[Co (L2) 2 (CH3OH)
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …

Two isomeric Co (II) complexes with the same general molecular formula of [Co (napy) 2
(NO3) 2](napy= 1, 8-naphthyridine) have been synthesized. X-ray single crystal structural …

In this work, the effects of ligand field strength as well as the metal coordination geometry on
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …

In this study, we report the syntheses and structures of two new mononuclear coordination
complexes ([Co (H2pimdc) 2 (phen)] n (1) and [Fe (H2pimdc) 2 (phen)] n (2), H2pimdc= 2 …

Three mononuclear six-coordinate Co (II)-pseudohalide complexes [Co (L) X2] with two N-
donor pseudohalido coligands occupying the cis-positions (X= NCS−(1), NCSe−(2) or N …